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Pyrolysis progress of oil sludge based on thermogravimetric Fourier transform infrared
CHEN Lei, YI Xiao-lu, SUN Lai-zhi, YANG Shuang-xia, XIE Xin-ping, HUA Dong-liang
Shandong Science    2021, 34 (5): 58-63.   DOI: 10.3976/j.issn.1002-4026.2021.05.008
Abstract248)      PDF(pc) (2187KB)(237)       Save
Oil sludge is one of the major solid wastes generated during oil field exploration, transportation, and petroleum refineries, which can cause severe soil, water, and air pollution. Pyrolysis is an effective technique for reducing oil sludge and achieving energy reutilization. Herein, the thermal characteristic mechanism and precipitation characteristics of oil sludge were studied using thermogravimetric Fourier transform infrared (TG-FTIR) analysis. Results show that the oil sludge pyrolysis process can be divided into three stages, namely, the release of water and a part of the light fraction, the release of organic materials, and the decomposition of carbonate compounds. The increase in the heating rate, affected by the delay in the internal heat and the mass transfer of oil sludge, led to the shift of the TG and derivative thermogravimetry (DTG) curves of the overall pyrolysis weight loss toward the high-temperature zone. Moreover, the pyrolysis process released CH4, CO, CO2, and volatile substances such as alkane, olefin, and aromatic hydrocarbons.
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Variationsin bacterial communities in the biodrying process of municipal excess sludge with CaO treatment
LIANG Xiao-hui , SI Hong-yu, ZHAO Yu-xiao, HUA Dong-liang, TANG Chun-hong , LI Rui-guo
Shandong Science    2020, 33 (6): 72-78.   DOI: 10.3976/j.issn.1002-4026.2020.06.010
Abstract253)      PDF(pc) (3054KB)(192)       Save
In this study, temperature, pH, and moisture content of the municipal excess sludge treated with CaO during the biodrying process were analyzed, and the obtained data were compared with excess sludge treated without CaO. It was observed that the sludge waste exhibited good buffering capacity of pH, and could improve the biodrying temperature to a certain degree after treated with CaO. Moreover, the variations in bacterial communities during the biodrying process of municipal excess sludge biodrying were analyzed based on two different conditions (with and without CaO treatment). It was found that the two different treatment methods and biodrying period had a significant effect on the bacterial communities in the sludge substrate. The study facilitates the preliminary foundation to further clarify the succession rules of microbial communities during municipal excess sludge biodrying using aerobic fermentation.
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Research progress of biomass gasification technology
GUAN Hai-bin, ZHANG Wei-jie, FAN Xiao-xu, ZHAO Bao-feng*, SUN Rong-feng,JIANG Jian-guo, DONG Hong-hai, XUE Xu-fang
SHANDONG SCIENCE    2017, 30 (4): 58-66.   DOI: 10.3976/j.issn.1002-4026.2017.04.010
Abstract610)      PDF(pc) (1022KB)(1127)       Save

As one of the important methods of clean and efficient exploitation of biomass, the biomass gasification technology has a broad development prospects. The domestic and abroad advances of biomass gasification technologies in recent years, such as gasifying agent gasification,pyrolysis gasification, catalytic gasification, plasma gasification, ultra supercritical water gasification, etc. were reviewed in the paper. Tar removal and purification, and the preparation of efficient catalysts are regarded as the two biggest obstacles to the biomass gasification, and the removal of tar by chemical method and the development of compound catalysts are suitable solutions to these problems. Finally, the largescale commercial utilization in certain industries is forecasted to be the main development trend of the biomass gasification.

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Gasification experiment of straw briquette fuel in a compound fixed bed
ZHANG Wei-jie,GUAN Hai-bin, JIANG Jian-guo, SUN Rong-feng, FAN Xiao-xu,YANG Li-guo,LIU Zuo, HU An-quan
SHANDONG SCIENCE    2017, 30 (4): 67-72.   DOI: 10.3976/j.issn.1002-4026.2017.04.011
Abstract277)      PDF(pc) (1248KB)(751)       Save

Using compound fixed bed pilot plant, and by adjusting the primary air volume, the two air volume and the feed quantity to control the temperature and the reaction depth of each reaction zone, the experimental study on the gasification of corn straw briquette fuel was carried out. The experimental results showed that the compound fixed bed had good adaptability to the straw briquette fuel, the temperature distribution in the furnace was reasonable, the stability of the chemical reaction equilibrium was achieved, and the gasification efficiency was as high as 75.4%. At the same time, the second air flow rate had obvious influence on the combustion temperature, as well as on the calorific value of gas in the gas combustion zone. Through the high temperature field of the tar cracking zone, tar in gas could be cracked in the furnace more completely, and the gas had a higher calorific value.

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Impact of ultralow temperature pretreatment on physical properties of cocoanut activated carbon
SI Hong-yu, YANG Li-jun, SUN Kun-yuan, LIANG Xiao-hui, ZHAO Yu-xiao, ZHANG Xiao-dong, ZHANG Yuan-cheng
SHANDONG SCIENCE    2016, 29 (6): 74-79.   DOI: 10.3976/j.issn.1002-4026.2016.06.012
Abstract344)      PDF(pc) (3182KB)(590)       Save

 To enhance absorption property of activated carbon and reduce energy consumption of preparation technology, we address the impact of ultralow temperature pretreatment on quality and preparation technology of activated carbon. We employ liquid nitrogen to pretreat coconut shell at ultralow temperature. Through rapid temperature rise, we prepare activated carbon at 600 ℃ whose specific surface area surpasses that of nonpretreatment activated carbon at 800 ℃. The specific surface area of activated carbon of the coconut shell increases to 2300 m2/g from 1 600 m2/g, and its micropore volume increases to 0.92 cm3/g from 0.67 cm3/g. Results show that ultralow temperature pretreatment has significant positive effect to quality improvement and reduction of energy consumption of activated carbon. The research provides reference for functional development and  the improvement of surface structure of activated carbon.

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Performance experiment of Nbutanol-gasoline blending fuel applied gasoline engine
AN Ming, FENG Hong-qing, LIU Dao-jian, ZHANG Jing, LI Dun, ZHANG Xiao-dong
SHANDONG SCIENCE    2016, 29 (6): 80-86.   DOI: 10.3976/j.issn.1002-4026.2016.06.013
Abstract350)      PDF(pc) (1518KB)(380)       Save

We conducted performance experiment for blending fuel of different blending ratios of nbutanol and gasoline applied port fuel injection engine. We compared pure gasoline and the blending fuel of blending ratios of 10% and 20% for 2 000 r/min and 2 500 r/min. Results show that the power of the engine slightly falls and BSFC increases a little. Specific fuel consumption is the lowest for torque moment of 90 N·m. For experimental condition, HC and NOx emission slightly decreases. The effect on CO emission is less.

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Research advances of biomass catalytic pyrolysis
MENG Guang-fan, SUN Lai-zhi, CHEN Lei, ZHAO Bao-feng, ZHANG Xiao-dong
SHANDONG SCIENCE    2016, 29 (4): 50-54.   DOI: 10.3976/j.issn.1002-4026.2016.04.011
Abstract506)      PDF(pc) (1086KB)(1078)       Save

We survey research advances of biomass catalytic pyrolysis from catalysts and regular reactors. It is still in experimental phase. Bio-oil ingredient after catalytic pyrolysis is still very complicated, difficult to separate its product and be fully utilized.Preparation of compound catalysts and amplification and design of a reactor are research emphasis in future.

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Resource utilization of protein alkali extraction from municipal residual sewage sludge
LIANG Xiao-hui,ZHANG Xiao-dong,SI Hong-yu,ZHAO Yu-xiao, HUA Dong-liang,WANG Bing-lian,YAN Yuan-yuan,YANG Li-jun,LU Yong
SHANDONG SCIENCE    2016, 29 (4): 55-59.   DOI: 10.3976/j.issn.1002-4026.2016.04.012
Abstract280)      PDF(pc) (1685KB)(885)       Save

We address protein extraction process of municipal residual sewage sludge.We initially compared acid and alkaline hydrolysis pretreatment methods and optimized the better alkaline hydrolysis method for protein extraction from municipal residual sludge. To acquire optimal extraction condition, we optimized NaOH concentration, solution amount and pretreatment time with response surface method.The optimal protein extraction condition is 21.79 g wet municipal sludge,80 mL NaOH solution (3.68 mol/L), and pretreatment time of 20.32 h at 50 ℃.The optimal protein extraction yield is 8 967±0.4 μg/g dry sludge, 2.33 times of initial extraction yield.

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Optimizing the biogas production from single-phase anaerobic fermentationof tomato stems and leaves using sludge
MU Hui, LI Yan, HUA Dong-liang, ZHANG Xiao-dong, XU Hai-peng, JIN Fu-qiang
SHANDONG SCIENCE    2016, 29 (3): 48-54.   DOI: 10.3976/j.issn.1002-4026.2016.03.009
Abstract275)      PDF(pc) (1964KB)(746)       Save

Due to the slow natural anaerobic fermentation characteristics of tomato stems and leaves, waste activated sludge was closed to be added into the digestor of tomato stems and leaves ( VS ratio of waste activated sludge and tomato stems and leaves of 12) to improve substrate nutrient composition. Anaerobic granular sludge of 0. 1 g/ mL was inoculated to compenstaes the deficiency of methanogenesis microbes. Under such regulation, the removal rate of tomato stems and leaves was increased to more than 95 %, and the corresponding biogas yield of organie fermentation was improved to 263 mL/ g ( 7. 5 times improvement) . Meanwhile, methane volume fraction in biogas was also increased by 64.5%. This method achieves not only the goal of waste control by waste, but also that of the maximization of resource utilization

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Advances on oriented thermalchemical conversion of biomass
XIE Xin-ping, ZHANG Xiao-dong,CHEN Lei, SUN Lai-zhi, YANG Shuang-xia, SI Hong-yu
SHANDONG SCIENCE    2016, 29 (3): 55-59.   DOI: 10.3976/j.issn.1002-4026.2016.03.010
Abstract550)      PDF(pc) (1008KB)(939)       Save

We review global advances of synthesis gas production through biomass gasification and high value-added chemicals production through biomass liquidation.Development of high activity, high selectivity and good stability catalyst is an urgent technical difficulty of biomass effective thermal-chemical conversion. For synthesis gas production through biomass gasification, development focus should be a catalyst of tar cracking and ratio adjustment of CO and H2 promotion. For high value-added chemicals production, a catalyst should reduce oxygen content in bio-oil, increase yield rate of required chemicals, and improve quality of bio-oil.

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Advances on influential factors of biogas anaerobic digestion progress
ZHANG Jie, ZHANG Xiaodong,XIAO Lin,LI Yan, HUA Dongliang,XU Haipeng,MU Hui,JIN Fuqiang,ZHAO Yuxiao,LIANG Xiaohui
SHANDONG SCIENCE    2016, 29 (1): 50-55.   DOI: 10.3976/j.issn.1002-4026.2016.01.009
Abstract363)      PDF(pc) (1142KB)(1699)       Save

Biogas anaerobic digestion (AD) process involves in synergy of complicated microorganism communities in anaerobic condition. Factors variation of the AD process may cause the variation of community composition, which may further affect stability and efficiency of a fermentation system. We address the factors affecting stability and efficiency of biogas AD process, including fermentation temperature,pH value,C/N ratio,OLR and retention time, macronutrients and trace elements.Mixed raw materials in AD process can compensate nutrient deficiency of single raw material and the impact of specific component accumulation on AD process stability. For temperature selection of AD process, if input and output energy ratio is fully considered, economy of AD process can be guaranteed.

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Cited: Baidu(1)
GC-MS analysis of main chemical components for biooil from three different biomass materials
LI Yanmei,BAI Xueyuan,YI Weiming
SHANDONG SCIENCE    2016, 29 (1): 56-61.   DOI: 10.3976/j.issn.1002-4026.2016.01.010
Abstract465)      PDF(pc) (1116KB)(1161)       Save

We perform pyrolysis experiments on a fixed bed reactor at 400, 450, 500 and 550 ℃ with corn straw, wheat straw and cotton straw as raw materials. We then obtain three biomassfastpyrolysis biooils. 500 ℃ is the optimal temperature for obtaining the highest average biooil yield. We further employ Gas ChromatographMass Spectrometercomputer (GC-MS)to determine their main chemical components and mass content at 500 ℃. Experimental results show that the kind of biomass materials has significant impact on biooil chemical components and contents. Biooil from every raw material has its own unique chemical compounds whose contents are also different. However, major components are approximately identical. Ketones are rich in biooil from corn stalk, and acids next. While acid is rich in biooil from wheat straw and cotton stalk, and ketones next.

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