CaO基催化剂在生物质热解中原位脱碳作用研究

doi:10.3976/j.issn.1002-4026.2019.05.011

Abstract

Abstract: An in-situ decarbonization process using CaO-based composite catalysts in biomass pyrolysis was investigated. The composition and content of the product gas were analyzed via gas chromatography. Results showed that the CaO-based composite catalysts could perform in-situ adsorption of CO₂ generated in biomass pyrolysis and thus achieve the targeted catalytic conversion of biomass. Using Fe-CaO and Ni-CaO composite catalysts in biomass pyrolysis, the liquid product yield could be reduced to less than 20%, whereas the gas product yield could be increased to as high as 67.1%. Under the catalytic pyrolysis condition of Ni-CaO, the H₂ content could reach 52.9%, whereas the φ(H2)/φ(CO) reached 2.6. Consequently, the quality of the pyrolysis gas improved.

Key words: CaO, composite catalysts, in-situ decarbonization, pyrolysis, biomass

CLC Number:

TQ426.8

XIE Xin-ping, CHEN Lei, SUN Lai-zhi, YANG Shuang-xia, YI Xiao-lu, HUA Dong-liang. In-situ CO₂ removal properties of CaO-based catalysts for biomass pyrolysis[J].Shandong Science, 2019, 32(5): 88-93.

References 17

1	ZHAO B F, ZHANG X D, CHEN L, et al. High quality fuel gas from biomass pyrolysis with calcium oxide[J]. Bioresource Technology, 2014, 156:78-83. doi: 10.1016/j.biortech.2014.01.031
2	HU G X, HUANG, H. Hydrogen rich fuel gas production by gasification of wet biomass using a CO2 sorbent[J]. Biomass & Bioenergy, 2009, 33 (5): 899-906.
3	MASNADI M S, GRACE J R, BI X T, et al. Biomass/coal steam CO-gasification integrated with in-situ CO2 capture[J]. Energy, 2015, 83:326-336. doi: 10.1016/j.energy.2015.02.028
4	WEI L G, XU S P, LIU J G, et al. Hydrogen production in steam gasification of biomass with CaO as a CO2 absorbent[J]. Energy & Fuels, 2008, 22 (3): 1997-2004. doi: 10.1021/ef700744a
5	LIU S M, ZHU J L, CHEN M Q, et al. Hydrogen production via catalytic pyrolysis of biomass in a two-stage fixed bed reactor system[J]. International Journal of Hydrogen Energy, 2014, 39(25):13128-13135. doi: 10.1016/j.ijhydene.2014.06.158
6	BAIDYA T, CATTOLICA R J. Fe and CaO promoted Ni catalyst on gasifier bed material for tar removal from producer gas[J]. Applied Catalysis A: General, 2015, 503:43-50. doi: 10.1016/j.apcata.2015.06.032
7	沈葵, 汪学广, 王新星, 等. 镁铝混合氧化物负载镍催化剂的制备及在液化石油气低温重整反应中的催化性能[J]. 高等学校化学学报, 2012, 33 (2) : 365-372. doi: 10.3969/j.issn.0251-0790.2012.02.027
8	ZHANG X D, YANG S X, XIE X P, et al. Stoichiometric synthesis of Fe/CaxO catalysts from tailored layered double hydroxide precursors for syngas production and tar removal in biomass gasification[J]. Journal of Analytical and Applied Pyrolysis, 2016, 120: 371-378. doi: 10.1016/j.jaap.2016.06.005
9	KUMAGAI S, ALVAREZ J, BLANCO P H, et al. Novel Ni-Mg-Al-Ca catalyst for enhanced hydrogen production for the pyrolysis-gasification of a biomass/plastic mixture[J]. Journal of Analytical and Applied Pyrolysis, 2015,113: 15-21. doi: 10.1016/j.jaap.2014.09.012
10	SUN L Z, ZHANG X D, CHEN L, et al. Effects of Fe contents on fast pyrolysis of biomass with Fe/CaO catalysts[J]. Journal of Analytical and Applied Pyrolysis, 2016, 119: 133-138. doi: 10.1016/j.jaap.2016.03.008
11	YANG S X, ZHANG X D, CHEN L, et al. Production of syngas from pyrolysis of biomass using Fe/CaO catalysts: Effect of operating conditions on the process[J]. Journal of Analytical and Applied Pyrolysis, 2017, 125: 1-8. doi: 10.1016/j.jaap.2017.05.007
12	ZAMBONI I, COURSON C, KIENNEMANN A. Synthesis of Fe/CaO active sorbent for CO2 absorption and tars removal in biomass gasification[J]. Catalysis Today, 2011, 176(1):197-201. doi: 10.1016/j.cattod.2011.01.014
13	FLORIN N H, HARRIS A T. Enhanced hydrogen production from biomass with in situ carbon dioxide capture using calcium oxide sorbents[J]. Chemical Engineering Science, 2008, 63(2):287-316. doi: 10.1016/j.ces.2007.09.011
14	谢新苹，张晓东，陈雷，等. 生物质定向热转化研究进展[J]. 山东科学, 2016, 29(3): 55-59. doi: 10.3976/j.issn.1002-4026.2016.03.010
15	WIDYAWATI M, CHURCH T L, FLORIN N H, et al. Hydrogen synthesis from biomass pyrolysis with in situ carbon dioxide capture using calcium oxide[J]. International Journal of Hydrogen Energy, 2011, 36(8):4800-4813. doi: 10.1016/j.ijhydene.2010.11.103
16	XUE A J, PAN J H, TIAN M C. Experimental study on catalytic pyrolysis of biomass pellet[J]. Applied Mechanics & Materials, 2013, 291/292/293/294: 320-323. doi: 10.4028/www.scientific.net/AMM.291-294.320
17	ZHOU Z M, QI Y, XIE M M, et al. Synthesis of CaO-based sorbents through incorporation of alumina/aluminate and their CO2 capture performance[J]. Chemical Engineering Science, 2012, 74: 172-180. doi: 10.1016/j.ces.2012.02.042

Metrics

Comments

Recommended 0

Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0), which permits third parties to freely share (i.e., copy and redistribute the material in any medium or format) and adapt (i.e., remix, transform, or build upon the material) the articles published in this journal, provided that appropriate credit is given, a link to the license is provided, and any changes made are indicated. The material may not be used for commercial purposes. For details of the CC BY-NC 4.0 license, please visit: https://creativecommons.org/licenses/by-nc/4.0

[1]	SONG Liuyang, SONG Wenlu, SUI Zhanbin, ZHANG Qi, WANG Jinguo. Ultrasound-induced mutation breeding of high lipid content Chlorella sp. [J]. Shandong Science, 2025, 38(4): 78-85.
[2]	WANG Chen, LU Yaxin, LI Xiaoyong, ZHANG Jiayi, XU Letian, FENG Qing. Effects of carbon-to-nitrogen ratio on the proliferation of typical salt-tolerant microorganisms [J]. Shandong Science, 2025, 38(2): 73-79.
[3]	XU Mengyu, WU Tianju, HUANG Lu, LIU Xin, ZHAO Jiarong, YOU Yuanyuan. Bioinformatics-based verification of the mechanism of Haitongpi-Tougucao in inhibiting ferroptosis in inflammatory chondrocytes [J]. Shandong Science, 2025, 38(1): 23-31.
[4]	CHEN Lei, YI Xiao-lu, SUN Lai-zhi, YANG Shuang-xia, XIE Xin-ping, HUA Dong-liang. Pyrolysis progress of oil sludge based on thermogravimetric Fourier transform infrared [J]. Shandong Science, 2021, 34(5): 58-63.
[5]	LIANG Xiao-hui , SI Hong-yu, ZHAO Yu-xiao, HUA Dong-liang, TANG Chun-hong , LI Rui-guo. Variationsin bacterial communities in the biodrying process of municipal excess sludge with CaO treatment [J]. Shandong Science, 2020, 33(6): 72-78.
[6]	LI Min, SUN Lai-zhi, CHEN Lei, YANG Shuang-xia, FENG Hong-qing, ZHANG Xiao-don. Biomass chemical looping gasification based on Fe/CaO oxygen carriers [J]. Shandong Science, 2019, 32(5): 94-103.
[7]	JIANG Jian-guo, ZHANG Wei-jie, SUN Rong-feng, GUAN Hai-bin, XU Min. Research progress on tar removal technology in biomass gasification process [J]. Shandong Science, 2019, 32(1): 127-134.
[8]	GUAN Hai-bin, ZHANG Wei-jie, FAN Xiao-xu, ZHAO Bao-feng*, SUN Rong-feng,JIANG Jian-guo, DONG Hong-hai, XUE Xu-fang. Research progress of biomass gasification technology [J]. SHANDONG SCIENCE, 2017, 30(4): 58-66.
[9]	MENG Guang-fan, SUN Lai-zhi, CHEN Lei, ZHAO Bao-feng, ZHANG Xiao-dong. Research advances of biomass catalytic pyrolysis [J]. SHANDONG SCIENCE, 2016, 29(4): 50-54.
[10]	XIE Xin-ping, ZHANG Xiao-dong,CHEN Lei, SUN Lai-zhi, YANG Shuang-xia, SI Hong-yu. Advances on oriented thermalchemical conversion of biomass [J]. SHANDONG SCIENCE, 2016, 29(3): 55-59.
[11]	LI Yanmei，BAI Xueyuan，YI Weiming. GC-MS analysis of main chemical components for biooil from three different biomass materials [J]. SHANDONG SCIENCE, 2016, 29(1): 56-61.
[12]	HANG Ruiqing, SUN Xiao,YANG Jianchao,SUN Qingtian,SUN Yanxia, JIANG Zhongwu. Impact of different N, P, K application rates on apple container seedling growth [J]. SHANDONG SCIENCE, 2016, 29(1): 98-104.
[13]	FANG Lu, QI Qiu-Yue, LI Bin, JIA Ze-Feng. Mycelial growth of fermentation medium of white Hypsizigus marmoreus and the optimization of exopolysaccharides medium [J]. J4, 2012, 25(1): 24-31.

In-situ CO₂ removal properties of CaO-based catalysts for biomass pyrolysis

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References 17

Related Articles 13

Metrics

Comments

Recommended 0

In-situ CO2 removal properties of CaO-based catalysts for biomass pyrolysis

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References 17

Related Articles 13

Metrics

Comments

Recommended 0

In-situ CO₂ removal properties of CaO-based catalysts for biomass pyrolysis