顶空固相微萃取结合气质联用方法快速测定地椒挥发性成分

doi:10.3976/j.issn.1002-4026.2022.01.001

Abstract

Abstract:

The headspace solid-phase microextraction (HS-SPME) method combined with gas chromatography-mass spectrometry (GC-MS) was used to extract and analyze the volatile components of Mongolian thyme herb,the peak areas were normalized to obtain the relative content of each component. A total of 56 volatile components were detected, of which, phenolic alcohols, terpenes, alkenes, esters, aldehydes, and ketones were the primary chemical compounds. linalool (27.8%), borneol (9.12%), camphor terpene (8.12%), limonene (7.81%), etc. were found to be the main ingredients. This is the first study wherein HS-SPME was performed in combination with GC-MS to analyze the volatile components of Mongolian thyme herb found in the Shandong area. The chemical components were found to be rich and have a high medicinal value.

Key words: Mongolian thyme herb, headspace solid-phase microextraction, gas chromatography-mass spectrometry

CLC Number:

R284.1

LI Qi-dong,ZHAO Jin,KONG Na,HUANG Lu-yao,PAN Shao-bin. Rapid analysis of the volatile components of Mongolian thyme herb's essential oils using headspace solid-phase microextraction combined with gas chromatography-mass spectrometry[J].Shandong Science, 2022, 35(1): 1-5.

Figures/Tables 2

References 26

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峰号	保留时间/min	保留指数RI	化合物名称	英文名称	分子式	分子量	面积归一化含量/%
1	8.09	965	3-蒈烯	3-carene	C₁₀H₁₆	136.23	5.36
2	8.39	979	樟脑萜	camphene	C₁₀H₁₆	136.23	8.12
3	8.97	1005	β-蒎烯	β-pinene	C₁₀H₁₆	136.23	2.54
4	9.26	1017	左旋-β-蒎烯	(1S)-(-)-β-Pinene	C₁₀H₁₆	136.23	2.82
7	10.22	1058	柠檬烯	cinene	C₁₀H₁₆	136.23	7.81
8	10.63	1075	罗勒烯	ocimene	C₁₀H₁₆	136.23	3.34
9	10.9	1087	γ-松油烯	γ-terpinene	C₁₀H₁₆	136.23	1.69
11	12.08	1134	芳樟醇	linalool	C₁₀H₁₈O	154.25	27.8
15	14.01	1210	龙脑	borneol	C₁₀H₁₈O	154.25	9.12
16	14.17	1215	松油烯-4-醇	terpinene-4-ol	C₁₀H₁₈O	154.25	2.76
25	16.04	1284	乙酸芳樟酯	linalyl acetate	C₁₂H₂₀O₂	196.29	1.91
32	20.43	1420	β-波旁烯	β-cyclobuta	C₁₅H₂₄	204.35	1.86
34	21.62	1456	β-石竹烯	β-caryophyllene	C₁₅H₂₄	204.35	3.52
41	23.6	1519	大根香叶烯 D	germacrene D	C₁₅H₂₄	204.35	3.35
42	24.02	1533	二环大根香叶烯	dicyclic macrogeraniene	C₁₅H₂₄	204.35	1.56
43	24.3	1543	金合欢烯	farnesene	C₁₅H₂₄	204.35	2.61

Rapid analysis of the volatile components of Mongolian thyme herb's essential oils using headspace solid-phase microextraction combined with gas chromatography-mass spectrometry

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