山东科学 ›› 2016, Vol. 29 ›› Issue (1): 56-61.doi: 10.3976/j.issn.1002-4026.2016.01.010

• 生物质能源 • 上一篇    下一篇

3种不同原料生物油主要化学成分的GC-MS分析

李艳美,柏雪源,易维明   

  1. 山东理工大学农业工程与食品科学学院,山东 淄博 255049
  • 收稿日期:2015-09-17 出版日期:2016-02-20 发布日期:2016-02-20
  • 作者简介:李艳美(1988-),女,博士研究生,研究方向为农村生物质能源与材料。Email:liyanmei0817@163.com
  • 基金资助:

    国家自然科学基金(51276103);国家高技术研究发展计划(863计划)(2012AA101808)

GC-MS analysis of main chemical components for biooil from three different biomass materials

LI Yanmei,BAI Xueyuan,YI Weiming   

  1. School of Agricultural Engineering and Food Science, Shandong University of Technology, Zibo 255049, China
  • Received:2015-09-17 Online:2016-02-20 Published:2016-02-20

摘要:

以玉米秸、麦秸和棉秆为原料,采用自制固定床热裂解反应器,在400、450、500和550 ℃等4个温度下进行了热裂解液化实验,获得了3种物料的生物油。反应温度为500 ℃时,3种生物质热裂解产油率最高。采用气质联用仪测定了500 ℃热裂解得到的3种原料生物油的化学组分和含量。结果表明,生物质原料种类对生物油的化学成分及含量的影响比较显著。每种原料制取的生物油都存在自己独有的化合物且含量也存在一定的差异,但主要化学族类大体相同。玉米秸热裂解油中酮类物质最多,酸类次之;麦秸和棉秆热裂解油中酸类物质居多,酮类物质次之。

关键词: 生物质, 热裂解, 生物油, 化学成分, 固定床反应器

Abstract:

We perform pyrolysis experiments on a fixed bed reactor at 400, 450, 500 and 550 ℃ with corn straw, wheat straw and cotton straw as raw materials. We then obtain three biomassfastpyrolysis biooils. 500 ℃ is the optimal temperature for obtaining the highest average biooil yield. We further employ Gas ChromatographMass Spectrometercomputer (GC-MS)to determine their main chemical components and mass content at 500 ℃. Experimental results show that the kind of biomass materials has significant impact on biooil chemical components and contents. Biooil from every raw material has its own unique chemical compounds whose contents are also different. However, major components are approximately identical. Ketones are rich in biooil from corn stalk, and acids next. While acid is rich in biooil from wheat straw and cotton stalk, and ketones next.

Key words: biomass, fixedreactor, bio-oil, chemical component, pyrolysis

中图分类号: 

  • TK6