生物质催化热解技术研究进展

doi:10.3976/j.issn.1002-4026.2016.04.011

山东科学 ›› 2016, Vol. 29 ›› Issue (4): 50-54.doi: 10.3976/j.issn.1002-4026.2016.04.011

生物质催化热解技术研究进展

孟光范，孙来芝*，陈雷，赵保峰，张晓东*

山东省生物质气化技术重点实验室，山东省科学院能源研究所，山东济南 250014

收稿日期:2016-06-16 出版日期:2016-08-20 发布日期:2016-08-20
通信作者: 孙来芝（1984-），男，博士，助理研究员，研究方向为生物质能技术。Email:sunlz@sderi.cn 张晓东（1977-），男，博士，研究员，研究方向为生物质能。Email:zhangxd@sderi.cn E-mail:sunlz@sderi.cn;zhangxd@sderi.cn
作者简介:孟光范（1982-），男，硕士，助理研究员，研究方向为生物质能技术。Email:menggf@sderi.cn
基金资助:
国家自然科学基金 (51276104)；山东省自然科学基金(ZR2014YL007，ZR2014YL041)

Research advances of biomass catalytic pyrolysis

MENG Guang-fan, SUN Lai-zhi*, CHEN Lei, ZHAO Bao-feng, ZHANG Xiao-dong*

Shandong Provincial Key laboratory of Biomass Gasification Technology, Energy Research Institute, Shandong Academy of Sciences, Jinan 250014, China

Received:2016-06-16 Online:2016-08-20 Published:2016-08-20

摘要/Abstract

摘要：

本文从生物质催化热解催化剂及常用反应器类型两个方面，综述了生物质催化热解技术的研究进展。目前此项技术仍处于实验室阶段，经催化热解提质后生物油品的成分仍非常复杂，产物难分离，无法高值化利用。制备复合型催化剂和进行反应器的放大与设计等是今后该领域的研究重点。

关键词: 催化剂, 生物质, 热解, 反应器

Abstract:

We survey research advances of biomass catalytic pyrolysis from catalysts and regular reactors. It is still in experimental phase. Bio-oil ingredient after catalytic pyrolysis is still very complicated, difficult to separate its product and be fully utilized.Preparation of compound catalysts and amplification and design of a reactor are research emphasis in future.

Key words: biomass, reactor, pyrolysis, catalyst

中图分类号:

TQ351.2

孟光范，孙来芝，陈雷，赵保峰，张晓东. 生物质催化热解技术研究进展[J]. 山东科学, 2016, 29(4): 50-54.

MENG Guang-fan, SUN Lai-zhi, CHEN Lei, ZHAO Bao-feng, ZHANG Xiao-dong. Research advances of biomass catalytic pyrolysis[J]. SHANDONG SCIENCE, 2016, 29(4): 50-54.

参考文献

［1］吴创之，马隆龙．生物质能现代化利用技术［M］．北京：化学工业出版社，2003.
［2］HUBER G W, IBORRA S, CORMA A. Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering ［J］. Chemical Reviews, 2006, 106(9): 4044-4098.
［3］WANG Z Y, WANG F, CAO J Q, et al. Pyrolysis of pine wood in a slowly heating fixedbed reactor: Potassium carbonate versus calcium hydroxide as a catalyst ［J］. Fuel Processing Technology, 2010, 91(8): 942-950.
［4］CAGLAR A, DEMIRBAS A. Conversion of cotton cocoon shell to liquid products by pyrolysis ［J］. Energy Conversion and Management, 2000, 41(16):1749-1756.
［5］NOWAKOWSKI D J, JONES J M, BRYDSON R, et al. Potassium catalysis in the pyrolysis behaviour of short rotation willow coppice ［J］. Fuel, 2007, 86(15): 2389-2402.
［6］PTN E. Catalytic pyrolysis of biomass: Effects of pyrolysis temperature, sweeping gas flow rate and MgO catalyst ［J］. Energy, 2010, 35(7):2761-2766.
［7］杨海平，陈汉平，杜胜磊,等．碱金属盐对生物质三组分热解的影响［J］．中国电机工程学报，2009，29(17):70-75.
［8］谭洪，王树荣，骆仲泱,等．金属盐对生物质热解特性影响实验研究［J］．工程热物理学报，2005，26(5):742-744.
［9］DEMIRBA??塁 A. Partly chemical analysis of liquid fraction of flash pyrolysis products from biomass in the presence of sodium carbonate ［J］. Energy Conversion and Management, 2002, 43(14): 1801-1809.
［10］LU Q, ZHANG Y, TANG Z, et al. Catalytic upgrading of biomass fast pyrolysis vapors with titania and zirconia /titania based catalysts ［J］. Fuel, 2010, 89(8): 2096-2103.
［11］WAN Y Q, CHEN P, ZHANG B, et al. Microwaveassisted pyrolysis of biomass: catalysts to improve product selectivity ［J］. Journal of Analytical and Applied Pyrolysis, 2009, 86(1):161-167．
［12］YORGUN S,SIMSEK Y E. Catalytic pyrolysis of Miscanthus × Giganteus over activated alumina ［J］. Bioresource Technology, 2008, 99(17):8095-8100.
［13］NOKKOSMAKI M I, KUOPPALA E T, LEPPAMAKI E A, et al. Catalytic conversion of biomass pyrolysis vapours with zinc oxide ［J］. Journal of Analytical and Applied Pyrolysis, 2000, 55(1):119-131.
［14］LU Q, ZHANG Z F,DONG C Q, et al. Catalytic upgrading of biomass fast pyrolysis vapors with nano metal oxides: An analytical Py-GC/MS study ［J］. Energies, 2010, 3(11)：1805-1820.
［15］ADAM J, BLAZS M. MSZROS E, et al. Pyrolysis of biomass in the presence of AlMCM41 type catalysts ［J］. Fuel, 2005, 84(12/13):1494-1502.
［16］AHO A, KUMAR N, ERANEN K, et al. Catalytic pyrolysis of woody biomass in a fluidized bed reactor: Influence of the zeolite structure ［J］. Fuel, 2008, 87(12): 2493-2501.
［17］ZHANG H Y,XIAO R,HUANG H, et al. Comparison of noncatalytic and catalytic fast pyrolysis of corncob in a fluidized bed reactor ［J］. Bioresource Technology, 2009, 100(3): 1428-1434.
［18］KELKAR S, SAFFRON C M,ANDREASSI K, et al. A survey of catalysts for aromatics from fast pyrolysis of biomass ［J］. Applied Catalysis B: Environmental, 2015,174/175: 85-95.
［19］FRENCH R,CZERNIK S. Catalytic pyrolysis of biomass for biofuels production ［J］. Fuel Processing Technology, 2010, 91(1): 25-32.
［20］PATTIYA A. TITILOYE J O, BRIDGWATER A V. Fast pyrolysis of cassava rhizome in the presence of catalysts ［J］. Journal of Analytical and Applied Pyrolysis, 2008, 81(1): 72-79.
［21］MIHALCIK D J, MULLEN C A, BOATENG A A. Screening acidic zeolites for catalytic fast pyrolysis of biomass and its components ［J］. Journal of Analytical and Applied Pyrolysis, 2011, 92(1):224-232.
［22］LU Q, XIONG W M, LI W Z, et al. Catalytic pyrolysis of cellulose with sulfated metal oxides: a promising method for obtaining high yield of light furan compounds ［J］. Bioresource Technology, 2009, 100(20):4871-4876.
［23］鲍卫仁，薛晓丽，曹青，等．MCM41/SBA15中孔分子筛对生物质热解油的催化裂解研究［J］．燃料化学学报，2006，34(6):675-679.
［24］鲁长波，宋文立，林伟刚．生物质催化热解催化剂稳定性考察［J］．石油学报（石油加工），2010，增刊:253-257.
［25］CARLSON T R,CHENG Y T,JAE J, et al. Production of green aromatics and olefins by catalytic fast pyrolysis of wood sawdust ［J］. Energy & Environmental Science, 2011, 4:145–161.
［26］SAMOLADA M C, PAPAFOTICA A, VASALOS I A. Catalyst evaluation forcatalytic biomass pyrolysis ［J］. Energy & Fuels, 2000, 14（6）: 1161-1167.
［27］陆强，李文志，张栋，等．锯末快速热解气的在线催化裂解［J］．化工学报，2009, 60(2)：351-357.
［28］LU Q, TANG Z, ZHANG Y, et al. Catalytic upgrading of biomass fast pyrolysis vapors with Pd/SBA15 Catalysts ［J］. Industrial & Engineering Chemistry Research, 2010, 49(6): 2573-2580.
［29］李凯，郑燕，龙潭，等．利用PyGC/MS研究温度和时间对生物质热解的影响［J］．燃料化学学报，2013, 41(7):845-849.
［30］SUN L Z,ZHANG X D, CHEN L, et al. Effects of Fe contents on fast pyrolysis of biomass with Fe/CaO catalysts ［J］. Journal of Analytical and Applied Pyrolysis, 2016, 119:133-138.

［31］SUN L Z,ZHANG X D,CHEN L, et al.Effect of preparation method on structure characteristics and fast pyrolysis of biomass with Fe/CaO catalysts ［J］. Journal of Analytical and Applied Pyrolysis, 2015, 116:183-189.
［32］ZHANG X D,SUN L Z,CHEN L, et al. Comparison of catalytic upgrading of biomass fast pyrolysis vapors over CaO and Fe(III)CaO catalysts ［J］. Journal of Analytical and Applied Pyrolysis, 2014, 108:35-40.
［33］王昶，郝庆兰，卢定强，等．生物质催化热解制取轻质芳烃［J］．催化学报，2008，29(9)：907-912.
［34］任铮伟，徐清，陈明强，等．流化床生物质快速裂解制液体燃料［J］．太阳能学报，2002, 23(4)：462-466.
［35］WILLIAMS P T, HORNE P A. The influence of catalyst regeneration on the composition of zeoliteupgraded biomass pyrolysis oils［J］. Fuel, 1995, 74(12): 1839-1851.

[1]	陈雷, 伊晓路, 孙来芝, 杨双霞, 谢新苹, 华栋梁. 基于热重-傅里叶红外联用的油泥砂热解过程[J]. 山东科学, 2021, 34(5): 58-63.
[2]	谢新苹, 陈雷, 孙来芝, 杨双霞, 伊晓路, 华栋梁. CaO基催化剂在生物质热解中原位脱碳作用研究[J]. 山东科学, 2019, 32(5): 88-93.
[3]	李敏, 孙来芝, 陈雷, 杨双霞, 冯洪庆, 张晓东. Fe/CaO载氧体作用下生物质化学链气化研究[J]. 山东科学, 2019, 32(5): 94-103.
[4]	姜建国, 张卫杰, 孙荣峰, 关海滨, 许敏. 生物质气化过程中焦油脱除技术研究进展[J]. 山东科学, 2019, 32(1): 127-134.
[5]	关海滨，张卫杰，范晓旭，赵保峰*，孙荣峰，姜建国，董红海，薛旭方. 生物质气化技术研究进展[J]. 山东科学, 2017, 30(4): 58-66.
[6]	谢新苹,张晓东,陈雷,孙来芝,杨双霞,司洪宇. 生物质定向热转化研究进展[J]. 山东科学, 2016, 29(3): 55-59.
[7]	李艳美，柏雪源，易维明. 3种不同原料生物油主要化学成分的GC-MS分析[J]. 山东科学, 2016, 29(1): 56-61.
[8]	蔡飞鹏, 王建梅, 王波. 生物质与煤气化特性的比较及对化工合成的影响[J]. J4, 2010, 23(2): 62-66.

生物质催化热解技术研究进展

Research advances of biomass catalytic pyrolysis

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 8

Metrics

本文评价

推荐阅读 0