高耐磨导静电石墨烯杂化材料/丁苯/顺丁胎面胶的研制

doi:10.3976/j.issn.1002-4026.20230083

Abstract

Abstract:

In this paper, graphene prepared by liquid-phase stripping assisted by tannic acid achieved better dispersion than ordinary graphene. The new graphene can meet the requirements of low cost, high output, and environmental protection. Graphene-SiO₂ hybrid materials were obtained by reacting SiO₂ treated with silane coupling agent (KH550) modification and graphene modified with tannic acid to form strong hybridization bonds, and the success of obtaining graphene-SiO₂hybrid materials was confirmed by infrared spectroscopy. Furthermore, the mechanical properties of graphene-SiO₂hybrid material in styrene-butadiene/polybutadiene composites were studied. In addition, the mechanical properties and the electrical and thermal conductivity of the blend of conductive carbon black and graphene-SiO₂ hybrid material in styrene-butadiene/polybutadiene composite were investigated. The results show that: at the addition of 1 part per hundred(phr) of graphene-SiO₂hybrid material, the butadiene/cis rubber composites obtained relatively good wear resistance, if the loading is more than 1 phr, the graphene fillers will easily reaggregate with each other, resulting in an increase in wear volume compared with the blank control group. Moreover, when 8 phrs of self-made graphene were added, the conductivity increased by 1 000 times, and the antistatic properties of rubber composites were considerably improved.

Key words: polybutadiene rubber, styrene-butadiene rubber, conductive carbon black, conductivity, wear resistance, graphene loading

CLC Number:

TQ328

TAN Shuangmei, GUAN Yingdong, ZHAO Shuai, LI Lin. Development of high wear resistant and electrostatic conductive graphene hybrid material/butylene/parabutylene tread rubber[J].Shandong Science, 2024, 37(2): 55-64.

Figures/Tables 7

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References 26

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编号	门尼黏度	MH/(dN·m)	ML/(dN·m)	(MH-ML)/(dN·m)	t₁₀/s	t₉₀/s	CRI/s^-1
1#	131	23.68	1.89	21.79	161	760	0.167
2#	148	27.88	3.56	24.32	34	602	0.176
3#	148	28.8	4.05	24.75	28	646	0.162
4#	153	27.22	5.32	21.90	61	809	0.134
5#	162	29.33	6.40	22.93	50	800	0.133
6#	172	31.33	5.76	25.57	34	902	0.115

Development of high wear resistant and electrostatic conductive graphene hybrid material/butylene/parabutylene tread rubber

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