J4 ›› 2011, Vol. 24 ›› Issue (3): 18-21.

• Content • Previous Articles     Next Articles

NHPI/MnSO4 catalyzed oxidation of p-Nitrotoluene to p-Nitrobenzoic acid

 ZHENG Li-Wen, CHEN Guan-Hong, KONG Xue, QIU Wei-Zhong, CHI Jian-Guo, WANG Jia-Ning   

  1. Shandong Provincial Key Laboratory of Applied Microbiology, Institute of Biology, Shandong Academy of Sciences, Jinan 250014, China
  • Received:2010-12-29 Published:2011-06-20 Online:2011-06-20

PDF (PC)

Like

Abstract:

       This paper presented NHPI/MnSO4 catalyzed oxidation of p-Nitrotoluene to p-Nitrobenzoic acid with glacial acetic acid as solvent and oxygen as an oxidant. We optimized the reaction conditions for this chemical reaction. The conversion rate of p-Nitrotoluene and the production rate of p-Nitrobenzoic acid reached 91.3% and 82.5% under these optimum conditions, so this catalytic reaction has better application prospect.

Key words: hydroxyphthalimide (NHPI), catalytic oxidation, p-Nitrotoluene, p-Nitrobenzoic acid

CLC Number: 

  • O625.61

Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0), which permits third parties to freely share (i.e., copy and redistribute the material in any medium or format) and adapt (i.e., remix, transform, or build upon the material) the articles published in this journal, provided that appropriate credit is given, a link to the license is provided, and any changes made are indicated. The material may not be used for commercial purposes. For details of the CC BY-NC 4.0 license, please visit: https://creativecommons.org/licenses/by-nc/4.0

鲁ICP备10205608号
Website Copyright © Editorial Office of Shandong Science
Tel: 0531-82605310　E-mail: xuxy@qlu.edu.cn
Powered by Beijing Magtech Co. Ltd