灶心土、生黄土及煅烧黄土的结构特征及挥发性成分对比研究

doi:10.3976/j.issn.1002-4026.2025179

Abstract

Abstract: In this study, scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and inductively coupled plasma optical emission spectrometry were employed to analyze the structural characteristics of Terra flava usta, raw loess, and calcined loess. Gas chromatography–ion mobility spectrometry (GC–IMS) was employed to compare differences in their volatile components. The results showed that wood-fired smoking induced fine-pore formation in Terra flava usta, increased the proportion of beneficial elements (Al, Fe, and Ca), and decreased the proportion of the harmful element Pt, shaping its specific structure and active component–loading capacity. A total of 45 volatile components were identified by GC–IMS. Wood-fired smoking caused degradation, volatilization, and re-adsorption of volatile components, altering the volatile-component profile of Terra flava usta. Partial least squares discriminant analysis identified 25 key differential components (VIP > 1.0), including sesamol, phellandrene, and limonene. Thus, wood-fired smoking is a key process that governs the fine-pore structure, active component–loading capacity, and volatile-component profile of Terra flava usta. This study provides a theoretical basis for understanding the pharmacodynamic basis underlying the traditional effects of Terra flava usta: “warming the middle energizer, drying dampness, and stopping and relieving bleeding.”

Key words: Terra Flava Usta, raw loess, calcined loess, structural characteristics, volatile constituent

CLC Number:

R283

WANG Zhenwu, LIU Shuang, DONG Hongjing, MI Yuzhang, GU Wenchao, ZHANG Liangkun, WANG Xiao, CHEN Jian. Comparative study of the structural characteristics and volatile components of Terra Flava Usta, raw loess, and calcined loess[J].Shandong Science, 0, (): 1-.

References

[1] 朱富民. 被遗忘的良药——灶心土[J]. 中国乡村医药, 2019, 26(17): 21. DOI:10.19542/j.cnki.1006-5180.003195.

[2] 唐铭霞, 曾慧敏, 钟钰, 等. 伏龙肝的本草考证和现代研究进展[J]. 中药药理与临床, 2025, 41(2): 100-108. DOI:10.13412/j.cnki.zyyl.20240320.008.

[3] 陈文文，钟恋，卢烽，等.灶心土的历史沿革及研究现状分析 [J]. 中药与临床，2021,12 (6):82-87.

[4] 王欢, 卫若楠, 朱向东. 灶心土的临床应用及其用量探究[J]. 吉林中医药, 2021, 41(12): 1665-1668. DOI:10.13463/j.cnki.jlzyy.2021.12.032.

[5] 杨倩倩, 张文霞, 孟子盈, 等. 土炒中药饮片的炮制工艺研究现状[J]. 中国民族民间医药, 2024, 33(7): 50-56. DOI:10.3969/j.issn.1007-8517.2024.07.zgmzmjyyzz202407012.

[6] 巩江, 骆蓉芳, 高昂, 等. 伏龙肝药学研究概况[J]. 安徽农业科学, 2010, 38(35): 20496. DOI:10.13989/j.cnki.0517-6611.2010.35.177.

[7] 赵玉升, 罗娟, 邢洪霞, 等. 伏龙肝中新型碳点的发现及其镇痛作用研究[J]. 中药材, 2019, 42(12): 2882-2886. DOI:10.13863/j.issn1001-4454.2019.12.028.

[8] 王小平, 谢伟容, 陈育青, 等. 不同产地的炮制辅料土中化学元素及水溶性盐含量测定[J]. 中国现代中药, 2020, 22(10): 1719-1725. DOI:10.13313/j.issn.1673-4890.20190905008.

[9] 王明芳, 孟祥龙, 何美菁, 等. 赤石脂和禹余粮作为灶心土替代品的分析[J]. 中国实验方剂学杂志, 2017, 23(6): 23-27. DOI:10.13422/j.cnki.syfjx.2017060023.

[10] 陈文文, 汤丹丹, 钟恋, 等. 基于UPLC-Q-Exactive MS技术的灶心土干预脾阳虚泄泻小鼠血清代谢组学研究[J]. 国际中医中药杂志, 2023, 45(5): 568-573. DOI:10.3760/cma.j.cn115398-20220707-00084.

[11] 杨俊玲, 刘艺, 木尼热·艾海提. 基于Box-Behnken响应面法优化肉豆蔻的炮制工艺[J]. 新疆中医药, 2025, 43(4): 54-57.

[12] 陈文文, 钟恋, 卢烽, 等. 基于肠道菌群的灶心土温脾止泻药效及机制研究[J]. 中药药理与临床, 2022, 38(1): 118-124.

[13] 毛银雪. 不同产地与基源石决明质量评价与煅制过程变化研究[D]. 连云港: 江苏海洋大学, 2022.

[14] 张敏, 潘志杰, 王晓琦, 等. 基于主成分分析降维-指纹图谱相似度约束的满意度函数值筛选二仙汤复合促渗剂[J]. 中草药, 2026, 57(7): 2501-2511. DOI:10.7501/j.issn.0253-2670.2026.07.007.

[15] 张建方, 陈宗良, 董莹盈, 等. Qams多成分定量及pca、opls-da、ew-topsis分析综合评价元宝草药材质量 [J]. 浙江中医药大学学报, 2024, 48(11): 1363-1376.

[16] 柳薇, 谭惠珍, 蒋立文, 等. 基于新型变量筛选-偏最小二乘判别分析方法的金银花与山银花近红外无损鉴别 [J]. 光谱学与光谱分析, 2025, 45(06): 1605-1611.

[17] 孙明霞, 郭亚南. D-柠檬烯通过激活Nrf2抗氧化系统抑制UVB诱导的小鼠皮肤光老化[J]. 中国皮肤性病学杂志, 2026, 40(1): 42-48. DOI:10.13735/j.cjdv.1001-7089.202412095.

[18] Xiao Shanshan, Yu Hang, Guo Yahui, et al. The antibacterial and anti-inflammatory potential of Cinnamomum camphora chvar. Borneol essential oil in vitro[J]. Plants, 2025, 14(12): 1880. DOI:10.3390/plants14121880.

[19] Petry J, Mai Han, Shoykhet M, et al. 1, 8-Cineole inhibits platelet-leukocyte aggregate formation by reducing P-selectin expression[J]. Frontiers in Pharmacology, 2025, 16: 1546157. DOI:10.3389/fphar.2025.1546157.

[20] 夏非, 邱智, 许孟操, 等. 薄荷酯的合成与应用研究进展[J]. 精细化工中间体, 2020, 50(5): 6-11. DOI:10.19342/j.cnki.issn.1009-9212.2020.05.002.

[21] 潘旭, 芦殿香, 华玉美多, 等. 水芹烯对去甲肾上腺素预收缩雄性大鼠肺小动脉、胸主动脉环的舒张作用及机制[J]. 中国高原医学与生物学杂志, 2025, 46(1): 1-13. DOI:10.13452/j.cnki.jqmc.2025.01.001.

[22] 徐欣雅, 谢允东. 芝麻酚对对乙酰氨基酚致肝损伤模型小鼠的保护作用及其机制[J]. 中国药业, 2025, 34(14): 42-45. DOI:10.3969/j.issn.1006-4931.2025.14.010.

[23] Shen Chunyan, Jiang Jianguo, Zhu Wei, et al. Anti-inflammatory effect of essential oil from Citrus aurantium L. var. amara engl[J]. Journal of Agricultural and Food Chemistry, 2017, 65(39): 8586-8594. DOI:10.1021/acs.jafc.7b02586.

Metrics

Comments

Recommended 0

Open Access This article is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License (CC BY-NC 4.0), which permits third parties to freely share (i.e., copy and redistribute the material in any medium or format) and adapt (i.e., remix, transform, or build upon the material) the articles published in this journal, provided that appropriate credit is given, a link to the license is provided, and any changes made are indicated. The material may not be used for commercial purposes. For details of the CC BY-NC 4.0 license, please visit: https://creativecommons.org/licenses/by-nc/4.0

Comparative study of the structural characteristics and volatile components of Terra Flava Usta, raw loess, and calcined loess

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 6

Metrics

Comments

Recommended 0

[1]	LI Zhiyong, LIU Jiangting, ZHANG Guoying, YANG Xueqi, ZHANG Mengxia, ZHAO Pan, ZHANG Xiuyun. Optimization of rice-fired Ganoderma lucidum processing by AHP-EWM and response surface methodology and comparative study on antioxidant activity before and after processing [J]. Shandong Science, 2026, 39(3): 1-11.
[2]	CAI Yuanyuan, DONG Hongjing, SHAO Rencai, LIU Feng. Effects of direct-contact ultrasonic vacuum drying on the drying characteristics and quality of dandelion [J]. Shandong Science, 2026, 39(1): 1-10.
[3]	ZHANG Wei, LIU Zhenyuan, DU Haochen, GUO Tiantian, YANG Mei, WANG Shandong, HAN Pei, SONG Xiangyun, ZHANG Guimin. Optimization of activated charcoal impurity removal process for Xiaojianzhong mixture and its impacton the stability of the mixture’s preparations [J]. Shandong Science, 2024, 37(4): 1-8.
[4]	WANG Yuchen, CUI Li, ZHAO Hengqiang, LU Heng, LIU Wei, WANG Xiao. Effect of different slicing methods on the drying characteristics of Salviae Miltiorrhizae Radix Et Rhizoma [J]. Shandong Science, 2023, 36(4): 10-17.
[5]	WANG Yu-zhen, GAO Shuang, SUN Yue, ZHANG Li, BO Fu-min, FENG An-jie, LI Ling-jun. Preparation process of chicoric acid liposome [J]. Shandong Science, 2020, 33(1): 8-15.
[6]	GUO Cheng-cheng, GAO Shuang, WANG Yu-zhen, XIE Hui-chao, MA Xue-mei, RONG Rong, YANG Yong, LI Ling-jun. Study on the preparation of cyclodextrin inclusion complex of volatile oil from Asarum by orthogonal tests [J]. Shandong Science, 2019, 32(2): 15-21.