辐射降温锦纶长丝及其针织物性能研究

doi:10.3976/j.issn.1002-4026.20240031

Abstract

Abstract:

Radiative-cooling nylon is a filament with a passive radiative cooling function and is made of high-infrared-emitting inorganic particle SiO₂and infrared-transmitting material polyamide 6 (PA6) using the industrial melt spinning method. In this study, the surface morphology, aggregated structure, chemical composition, mechanical properties, thermal properties, and surface friction properties of three types of radiative-cooling nylon filaments and an ordinary nylon filament were compared. The thermal conductivity, cool feeling at instant contact, and indoor cooling performance of the four knitted fabrics were further tested. The results show that the knitted fabric interwoven with the radiative-cooling PA6/PE sheath-core composite yarn, which is spun with SiO₂-added radiative-cooling PA6 as the skin material and polyethylene (PE) as the core material, and radiative-cooling nylon filament with circular cross-section demonstrate the best thermal conductivity and cooling performance. Its infrared thermal imaging temperature was approximately 1.8 ℃ higher than that of the ordinary nylon knitted fabric, indicating that the knitted fabric exhibits a higher infrared transmittance and better cooling effect. Thus, the radiative-cooling nylon knitted fabric possesses excellent radiative cooling performance and wearability and can be used for the development of radiative-cooling textiles.

Key words: radiative cooling, nylon filament, silica powder, fabric performance

CLC Number:

TS102.5

HUANG Jing, BAI Zhihao, WU Ke, DU Lixin, ZHANG Ruiyun, LI Hong, HUANG Liqian. Properties of radiative-cooling nylon filaments and their knitted fabrics[J].Shandong Science, 2024, 37(4): 65-74.

Figures/Tables 12

Fig.1

Fig.2

Table 1

Fig.3

Fig.4

Table 2

Fig.5

Table 3

Fig.6

Fig.7

Fig.8

Fig.9

References 32

[1]	曾少宁, 胡佳雨, 张曼妮, 等. 面向个人热管理的降温纺织品[J]. 科学通报, 67(11):1167-1179.DOI: 10.1360/TB-2021-1126.
[2]	PENG Y C, CUI Y. Advanced textiles for personal thermal management and energy[J]. Joule, 2020, 4(4): 724-742.DOI:10.1016/j.joule.2020.02.011.
[3]	ZHAO M M, GAO C S, WANG F M, et al. A study on local cooling of garments with ventilation fans and openings placed at different torso sites[J]. International Journal of Industrial Ergonomics, 2013, 43(3): 232-237. DOI: 10.1016/j.ergon.2013.01.001.
[4]	GUO T H, SHANG B F, DUAN B, et al. Design and testing of a liquid cooled garment for hot environments[J]. Journal of Thermal Biology, 2015, 49/50: 47-54. DOI: 10.1016/j.jtherbio.2015.01.003.
[5]	CAI G M, YANG N, LIU H X, et al. Single-phased and color tunable LiSrBO 3: Dy₃ +, Tm₃ +, Eu₃ + phosphors for white-light-emitting application[J]. Journal of Luminescence, 2017, 187: 211-220. DOI: 10.1016/j.jlumin.2017.03.017.
[6]	刘文陶. 复合纤维及其冷感织物: CN205368621U[P]. 2016-07-06.
[7]	黄宜坤, 翁鸣, 陈红伟, 等. 凉感纤维用改性聚乙烯切片的制备与性能[J]. 浙江理工大学学报(自然科学版), 2023, 49(1): 1-8.
[8]	王雪, 李娜娜, 徐密, 等. 导湿凉感织物结构设计与性能测试[J]. 针织工业, 2021(1): 16-20.
[9]	季成龙. 基于纳米氮化硼吸湿凉爽面料的开发[D]. 上海: 东华大学, 2019.
[10]	SUN Y L, JI Y T, JAVED M, et al. Preparation of passive daytime cooling fabric with the synergistic effect of radiative cooling and evaporative cooling[J]. Advanced Materials Technologies, 2022, 7(3): 2100803. DOI: 10.1002/admt.202100803.
[11]	ZHONG S J, YI L M, ZHANG J W, et al. Self-cleaning and spectrally selective coating on cotton fabric for passive daytime radiative cooling[J]. Chemical Engineering Journal, 2021, 407: 127104. DOI: 10.1016/j.cej.2020.127104.
[12]	ZENG S, PIAN S, SU M, et al. Hierarchical-morphology metafabric for scalable passive daytime radiative cooling[J]. Science, 2021, 373(6555): 692-696. doi: 10.1126/science.abi5484 pmid: 34353954
[13]	张小双, 李耀刚, 张青红, 等. SiO₂/PA6辐射降温长丝及其织物的制备及性能研究[J]. 化工新型材料, 2023, 51(2): 235-238. DOI: 10.19817/j.cnki.issn1006-3536.2023.02.047.
[14]	林海, 李雪梅, 黄洁希. PE/PA6皮芯型复合纤维的纺制[J]. 化纤与纺织技术, 2017, 46(1): 1-5. DOI: 10.3969/j.issn.1672-500x.2017.01.001.
[15]	中国纺织工业协会. 化学纤维长丝拉伸性能试验方法:GB/T 14344—2008 [S]. 北京: 中国标准出版社, 2008.
[16]	中国纺织总会. 纺织品和纺织制品厚度的测定:GB/T3820—1997 [S]. 北京: 中国标准出版社,1997.
[17]	中国纺织工业联合会. 纺织品生理舒适性稳态条件下热阻和湿阻的测定( 蒸发热板法):GB/T 11048—2018[S]. 北京: 中国标准出版社, 2018.
[18]	中国纺织工业联合会. 纺织品接触瞬间凉感性能的检测和评价:GB/T 35263—2017[S]. 北京: 中国标准出版社, 2017.
[19]	李勇翰, 刘燕, 柏志豪, 等. 纱线与组织结构对机织物凉爽性能影响[J]. 山东科学, 2024, 37(1):80-87.DOI:10.3976/j.issn.1002-4026.20230065.
[20]	刘杰, 赵中楠. 石墨烯改性锦纶的结构与性能研究[J]. 棉纺织技术, 2021, 49(9): 15-18. DOI: 10.3969/j.issn.1001-7415.2021.09.004.
[21]	王丹, 董文, 刘亚军, 等. 纳米氧化锌改性PA6复合材料的制备及性能研究[J]. 胶体与聚合物, 2009, 27(3): 24-26. DOI: 10.3969/j.issn.1009-1815.2009.03.007.
[22]	张迅, 钟申洁, 张佳文, 等. 具有日间被动辐射制冷功能的超疏水锦纶6织物的制备及性能研究[J]. 丝绸, 2022, 59(2): 31-39.DOI:10.3969/j.issn.10017003.2022.02.005.
[23]	赵凯敏, 刘夙. 不同参数高强高模针织物拉伸性能研究[J]. 中国纤检, 2022(2): 107-110. DOI: 10.14162/j.cnki.11-4772/t.2022.02.034.
[24]	李顺希, 许志强, 詹莹韬, 等. 高密度聚乙烯/聚酰胺6复合纤维的制备及性能[J]. 合成纤维工业, 2020, 43(1): 42-45. DOI: 10.3969/j.issn.1001-0041.2020.01.009.
[25]	赵晓敏. 凉感聚酰胺6纤维的制备及性能评价[D].上海:东华大学2017.
[26]	程明丽, 沈为, 俞灏, 等. 吸湿发热针织物的热湿性能研究[J]. 东华大学学报(自然科学版), 2022, 48(6): 57-63. DOI: 10.19886/j.cnki.dhdz.2021.0601.
[27]	王启明, 陈力群, 许贻东, 等. 吸湿凉感纬编针织面料开发[J]. 针织工业, 2018(9): 9-14. DOI: 10.3969/j.issn.1000-4033.2018.09.003.
[28]	冯隆隆, 谢冰冰, 张瑞云, 等. 依翡丝纤维及其织物性能研究[J]. 山东科学, 2023, 36(3):60-68. DOI:10.3976/j.issn.1002-4026.2023.03.008.
[29]	肖润财. 基于纳米纤维材料的人体辐射降温织物[D]. 上海: 东华大学, 2020.
[30]	杨春利, 商胜龙, 刘云. PTFE-PVDF/SiO₂导电织物制冷/保暖双功能纺织品的制备及性能研究[J]. 化工新型材料, 2023, 51(8): 128-133. DOI: 10.19817/j.cnki.issn1006-3536.2023.08.025.
[31]	郑晶晶. 冬季用围巾保暖性能评价[J]. 纺织学报, 2017, 38(12): 129-134. DOI: 10.13475/j.fzxb.20170200306.
[32]	袁帅霞. 天然纤维素基日间被动辐射制冷材料的制备及应用研究[D]. 杭州: 浙江理工大学, 2022.

长丝编号	w(C)/%	w(N)/%	w(O)/%	w(Si)/%
L	64.75	17.98	17.27	0
L1	64.10	16.49	17.95	1.46
L2	65.60	16.06	16.56	1.78
L3	66.36	16.91	15.76	0.97

长丝编号	断裂强力/cN	断裂强度/(cN·tex^-1)	断裂伸长率/%
L	362.77	46.51	41.41
L1	346.18	44.38	32.17
L2	355.71	45.60	31.08
L3	322.43	41.34	41.67

试样编号	长丝编号	组织结构	厚度/mm	面密度/(g·m^-2)	横密^*	纵密^*	表观孔隙率/%
A1	L	纬平针	0.63	105.69	125	130	1.598
A2	L1	纬平针	0.74	112.41	112	115	0.915
A3	L2	纬平针	0.67	97.94	110	115	1.668
A4	L1/L3	一隔一纬平针	0.51	119.69	105	110	11.875

Properties of radiative-cooling nylon filaments and their knitted fabrics

RichHTML

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 12

References 32

Related Articles 2

Metrics

Comments

Recommended 0

[1]	FENG Longlong, XIE Bingbing, ZHANG Ruiyun, LU Jian, YU Hao, WANG Yunhai. Properties of the Exfresh fiber and its fabrics [J]. Shandong Science, 2023, 36(3): 60-68.
[2]	XIE Bingbing, FENG Longlong, ZHANG Ruiyun, FANG Bin, WU Zhiping. Comparison of structure and properties of EKS and acrylic fibers [J]. Shandong Science, 2023, 36(3): 69-77.