芳纶短纤维/芳纶浆粕增强制备高性能氯丁橡胶复合材料

doi:10.3976/j.issn.1002-4026.2018.04.009

SHANDONG SCIENCE ›› 2018, Vol. 31 ›› Issue (4): 50-58.doi: 10.3976/j.issn.1002-4026.2018.04.009

• New Materials • Previous Articles Next Articles

Effect of aramidshort fiber and aramid pulp on the structure and properties of rubber composites

CHEN Chun-hua, XU Zhan, SHEN Bin, XIN Zhen-xiang

Key Laboratory of RubberPlastics, Ministry of Education, Qingdao University of Science and Technology,Qingdao 266042, China

Received:2018-04-02 Online:2018-08-20 Published:2018-08-20

Abstract

Abstract:

In this paper, the microstructure characterization and thermal weight loss analysis of aramid short fiber and aramid pulp were carried out. The effects of aramid short fiber/aramid pulp on the basic physical properties, dynamic mechanical properties and dynamic stiffness of the rubber composites were systematically studied. The results show that, aramid fiber has a giant fibrous model, and Kevlar pulp has microfiber model. The degradation of aramid staple fibers at 500 ℃ was basically complete at about 650 ℃. The aramid pulp was degraded at about 350 ℃ and degraded quickly at about 500 ℃, and the degradation was basically complete at about 650 ℃. The smaller the ratio of aramid short fiber/aramid pulp is, the greater the tear strength and elongation, the better the flexural properties of the rubber composite, but the smaller the dynamic stiffness. The dynamic mechanical properties show that when the ratio of aramid fiber and aramid pulp is 10:10, it has relatively higher storage modulus, lower loss modulus and loss factor, and better dynamic fatigue performance.

Key words: aramid short fiber, composites, aramid pulp, dynamic stiffness

CLC Number:

TQ330.1⁺2

CHEN Chun-hua, XU Zhan, SHEN Bin, XIN Zhen-xiang. Effect of aramidshort fiber and aramid pulp on the structure and properties of rubber composites[J].SHANDONG SCIENCE, 2018, 31(4): 50-58.

References

［1］唐爱民, 王鑫, 陈港. 超声波作用下对位芳纶纤维的超微结构[J].高分子材料科学与工程，2011，27( 7) : 2730．
[2]. ALWIS K G N C, BURGOYNE C J. Timetemperature superposition to determine the stress rupture of aramid fibers[J]. Applied Composite Materials, 2006, 13（4）: 249264.
[3]张志成, 郑元锁. 橡胶基复合材料中的短纤维长径比及其分布[J]. 西安交通大学学报, 2002, 36(7) : 761764.
[4]ZHANG B, GU B Q, YU X M. Failure behavior of resorcinolformaldehyde latex coated shortfiberreinforced rubber sealing under transverse tension[J]. Journal of Applied Polymer Science, 2015, 132(12): 41672.
[5]王曙中. 芳纶浆粕的现状及其应用前景[J]. 高科技纤维与应用, 2003, 28(3): 1417.
[6]马岩, 逄见光, 朱超, 等. 芳纶短纤维对氢化丁腈橡胶复合材料性能的影响[J].高分子材料科学与工程，2017，33(9): 2934.
[7]KATO T, MAGARIO A. The wear of aramid fiber reinforced brake pads: the role of aramid fibers[J]. Tribology Transactions, 1994, 37(3): 559565.
[8]GOPAL P, DHARANI L R, BLUM F D. Hybrid phenolic friction composites containing Kevlar pulp Part 1. Enhancement of friction and wear performance[J]. Wear, 1996, 193(2): 199206.
[9]中华人民共和国国家质量监督检验检疫总局，中国国家标准化管理委员会. GB/T 531.1—2008 硫化橡胶或热塑性橡胶压入硬度试验方法第1部分：邵氏硬度计法(邵尔硬度) [S]. 北京：中国标准出版社, 2008.
[10]中华人民共和国国家质量监督检验检疫总局，中国国家标准化管理委员会. GB/T 528—2009 硫化橡胶或热塑性橡胶拉伸应力应变性能的测定[S]. 北京：中国标准出版社, 2009.
[11]中华人民共和国国家质量监督检验检疫总局，中国国家标准化管理委员会. GB/T 529—2008硫化橡胶或热塑性橡胶撕裂强度的测定(裤形、直角形和新月形试样)[S].北京：中国标准出版社, 2008.
[12]中华人民共和国国家质量监督检验检疫总局，中国国家标准化管理委员会. GB/T 13934—2006硫化橡胶或热塑性橡胶屈挠龟裂和裂口增长的测定(德墨西亚型)[S].北京：中国标准出版社, 2006.
[13]中华人民共和国国家质量监督检验检疫总局，中国国家标准化管理委员会. GB/T 9867—2008硫化橡胶或热塑性橡胶耐磨性能的测定(旋转辊筒式磨耗机法) [S].北京：中国标准出版社, 2008.

Effect of aramidshort fiber and aramid pulp on the structure and properties of rubber composites

PDF (PC)

Like

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 0

Metrics

Comments

Recommended 0