山东科学 ›› 2024, Vol. 37 ›› Issue (6): 83-93.doi: 10.3976/j.issn.1002-4026.20240029

• 新材料 • 上一篇    下一篇

邻苯二甲腈树脂研究及应用进展

朱光来1(), 于一涛1, 刘强1, 刘海明3, 侯衍涛1, 许超2, 张维2, 姜传兴2, 李元月2, 潘新敬4, 李冰1,*(), 王振华5,*()   

  1. 1.齐鲁工业大学(山东省科学院) 新材料研究所 山东省轻质高强金属材料省级重点实验室,山东 济南 250022
    2.山东省产品质量检验研究院,山东 济南 250102
    3.潍坊市产品质量检验所,山东 潍坊 261000
    4.山东省昌乐一中,山东 潍坊 262400
    5.齐鲁工业大学(山东省科学院) 山东省分析测试中心,山东 济南 250014
  • 收稿日期:2024-02-29 出版日期:2024-12-20 发布日期:2024-12-05
  • 通信作者: *李冰(1979—),男,副研究员,研究方向为高分子材料的开发与应用。E-mail:mindless000cn@163.com, Tel:13678825051; 王振华(1975—),男,研究员,研究方向为环境工程材料。E-mail:wzh312@mail.sdu.edu.cn
  • 作者简介:朱光来(1999—),男,硕士研究生,研究方向为邻苯二甲腈树脂的开发与应用。E-mail:zhuguanglai369@163.com
  • 基金资助:
    内蒙古自治区科技重大专项(2021ZD0007)

Research and application progress of phthalonitrile resin

ZHU Guanglai1(), YU Yitao1, LIU Qiang1, LIU Haiming3, HOU Yantao1, XU Chao2, ZHANG Wei2, JIANG Chuanxing2, LI Yuanyue2, PAN Xinjing4, LI Bing1,*(), WANG Zhenhua5,*()   

  1. 1. Key Laboratory for Light and High Strength Metal Materials of Shandong Province, Institute of New Materials, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250022, China
    2. Shandong Institute of Product Quality Inspection, Jinan 250102, China
    3. Weifang Institute of Product Quality Inspection, Weifang 261000, China
    4. No.1 Middle School of Changle Shandong, Weifang 262400, China
    5. Shandong Analysis and Test Center,Qilu University of Technology (Shandong Academy of Sciences), Jinan 250014, China
  • Received:2024-02-29 Online:2024-12-20 Published:2024-12-05

摘要:

邻苯二甲腈树脂是一类新型的耐高温热固性树脂体系,因其具有优异的热氧稳定性、阻燃性、力学性能、低膨胀系数、低介电常数和低介电损耗而受到广泛关注。为了改善其工艺性并满足严苛的环境性能需求,国内外针对邻苯二甲腈树脂体系开展了大量改性研究工作。从分子结构设计、固化方式、固化机理及其在电子领域和粘接领域的应用等方面,介绍了邻苯二甲腈体系的研究进展,并对邻苯二甲腈作为新型特种功能树脂材料所面临的机遇与挑战做了展望,以期对相关领域的研究提供参考。

关键词: 邻苯二甲腈, 树脂, 分子结构, 粘接

Abstract:

Phthalonitrile resin is new type of high-temperature resistant thermosetting resin system that has attracted wide attention owing to its excellent thermal and oxidative stability, flame retardancy, and mechanical properties as well as low expansion coefficient, dielectric constant, and dielectric loss. To improve its manufacturability and meet stringent environmental performance requirements, extensive research has been conducted worldwide on the modification of the phthalonitrile system. This paper reviews the research progress of the phthalonitrile system from the aspects of molecular structure design and curing methods and mechanisms along with its applications in electrical components, adhesives, etc. Moreover, the paper discusses the opportunities and challenges faced by phthalonitrile as a new type of special functional resin material, aiming to provide insights for research in relevant fields.

Key words: phthalonitrile, resin, molecular structure, adhesive

中图分类号: 

  • TQ322.41

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