胜利油田石油污染土壤中重金属的形态分析

doi:10.3976/j.issn.1002-4026.2015.04.011

山东科学 ›› 2015, Vol. 28 ›› Issue (4): 58-64.doi: 10.3976/j.issn.1002-4026.2015.04.011

胜利油田石油污染土壤中重金属的形态分析

傅晓文1，陈贯虹1，迟建国1，邱维忠1，王加宁1*，崔兆杰2

1.山东省科学院生物研究所，山东济南 250014；2.山东大学环境科学与工程学院，山东济南 250100

收稿日期:2015-06-15 出版日期:2015-08-20 发布日期:2015-08-20
通信作者: 王加宁 E-mail:wangjn@sdas.org
作者简介:傅晓文（1984  ），男，博士，研究方向为环境监测与评价。
基金资助:
山东省科学院先导科技专项（2013）；山东省环境瓶颈解析与突破项目（SDHBPJZB07）

Speciation analysis of heavy metals in oilpolluted soil of Shengli Oilfield

FU Xiaowen, CHEN Guanhong, CHI Jianguo, QIU Weizhong, WANG Jianing, CUI Zhaojie

1.Biology Institute, Shandong Academy of Sciences, Jinan 250014, China; 2.School of Environmental Science and Engineering, Shandong University, Jinan 250100, China

Received:2015-06-15 Online:2015-08-20 Published:2015-08-20

摘要/Abstract

摘要： 长期油田开发导致了胜利油田土壤环境的逐渐恶化，掌握伴随石油污染的土壤重金属累积和存在情况是弄清该地区土壤环境质量问题的关键之一。本文以胜利油田孤岛油区为研究区，通过改进的BCR连续提取法和DTPA提取法分别分析了土壤中4种重金属（Zn、Pb、Cd和Ni）的形态组成和有效态含量，指出研究区土壤中Zn和Cd具有较高活性和生物有效性，存在潜在污染风险。另一方面，通过分析不同年代开发的油井周围土壤中重金属的有效态含量，指出Cd和Ni的来源和形态分布可能受到了石油污染的影响。

关键词: 有效态, 重金属, 土壤, 形态分析, 油田

Abstract: Longterm crude oil exploitation has led to soil deterioration in Shengli Oilfield.Knowledge about accumulation and speciation of heavy metals in oilpolluted soil is the key to clear understanding of soil quality issue at this region.We analyze the speciation and content of 4 heavy metals (Zn, Pb, Cd and Ni) through modified BCR and DTPA extraction methods, taking the soil of Gudao oil region as an example.Results reveal that Zn and Cd have higher activity and bioavailability in the soil, so potential pollution risk exists.On the other hand, we discover that the source and speciation of Cd and Ni are probably affected by oil pollution in the soil by analysis of available form of heavy metals in well soil of different exploitation ages.

Key words: oil field, heavy metals, soil, speciation analysis, available form

中图分类号:

X833

傅晓文，陈贯虹，迟建国，邱维忠，王加宁，崔兆杰. 胜利油田石油污染土壤中重金属的形态分析[J]. 山东科学, 2015, 28(4): 58-64.

FU Xiaowen, CHEN Guanhong, CHI Jianguo, QIU Weizhong, WANG Jianing, CUI Zhaojie. Speciation analysis of heavy metals in oilpolluted soil of Shengli Oilfield[J]. SHANDONG SCIENCE, 2015, 28(4): 58-64.

参考文献

［1］AMADI A, ABBEY SD, NMA A.Chronic effects of oil spill on soil properties and microflora of a rainforest ecosystem in Nigeria ［J］.Water, Air, & Soil Pollution, 1996，86(1): 1-11. ［2］ PENG S, ZHOU Q, CAI Z,et al.Phytoremediation of petroleum contaminated soils by Mirabilis jalapa L.in a greenhouse plot experiment ［J］.Journal of hazardous materials, 2009,168(2/3): 1490-1496. ［3］姜昌亮.石油污染土壤的物理化学处理——生物修复工艺与技术研究［D］.沈阳: 中国科学院应用生态研究所.2001. ［4］刘五星, 骆永明, 滕应, 等.我国部分油田土壤及油泥的石油污染初步研究［J］.土壤, 2007， 39(2): 247-251. ［5］ YEN T F.Role of trace metals in petroleum［M］.Ann Arbor, MI: Ann Arbor Science Publishers.1975：215. ［6］刘长久, 张广林.石油和石油产品中非烃化合物［M］.北京: 中国石化出版社，1991. ［7］笠松喬介.石油中の金属 (分析特集号) ［J］.三菱石油株式会社技術資料, 1966,16(2): 65-72. ［8］ CARLS E G, FENN D B, CHAFFEY S A.Soil contamination by oil and gas drilling and production operations in Padre Island National Seashore, Texas, USA ［J］.Journal of environmental management, 1995,45(3): 273-286. ［9］ KISIC I, MESIC S, BASIC F, et al.The effect of drilling fluids and crude oil on some chemical characteristics of soil and crops ［J］.Geoderma, 2009,149(3): 209-216. ［10］ NIE M, XIAN N, FU X, et al.The interactive effects of petroleumhydrocarbon spillage and plant rhizosphere on concentrations and distribution of heavy metals in sediments in the Yellow River Delta, China ［J］.Journal of hazardous materials, 2010,174(1/2/3): 156-161. ［11］ OSUJI L C, ADESIYAN S O.Extractable hydrocarbons, nickel and vanadium contents of ogbodoisiokpo oil spill polluted soils in Niger Delta, Nigeria ［J］.Environmental monitoring and assessment, 2005,110(1): 129-139. ［12］ OSUJI L C, ONOJAKE C M.Trace heavy metals associated with crude oil: A case study of Ebocha‐8 oil‐spill‐polluted site in Niger Delta, Nigeria ［J］.Chemistry & biodiversity, 2004,1(11): 1708-1715. ［13］ OSUJI L C, ONOJAKE C M.Field reconnaissance and estimation of petroleum hydrocarbon and heavy metal contents of soils affected by the Ebocha8 oil spillage in Niger Delta, Nigeria ［J］.Journal of environmental management, 2006,79(2): 133-139. ［14］ DORAN J W.Soil health and global sustainability: Translating science into practice ［J］.Agriculture, ecosystems & environment, 2002, 88(2): 119-127. ［15］ FRSTNER U, WITTMANN G T, PROSI F,et al.Metal pollution in the aquatic environment［M］.Berlin: Springer,1979. ［16］顾继光, 周启星, 王新.土壤重金属污染的治理途径及其研究进展［J］.应用基础与工程科学学报, 2003, 11(2): 143-151. ［17］孙铁珩, 宋玉芳.土壤污染的生态毒理诊断［J］.环境科学学报, 2002, 22(6): 689-695. ［18］李丕龙.胜利油区勘探现状及展望［J］.油气地质与采收率, 2002, 9(1): 9-12. ［19］王代流, 蒋予岭, 耿志国,等.孤岛低品位稠油开采配套技术［J］.石油天然气学报, 2012， 34(10): 121-124. ［20］ WALKLEY A, BLACK I A.An examination of the Degtjareff method for determining soil organic matter, and a proposed modification of the chromic acid titration method ［J］.Soil Science, 1934， 37(1): 29-38. ［21］ ADENIYI A A, AFOLABI J A.Determination of total petroleum hydrocarbons and heavy metals in soils within the vicinity of facilities handling refined petroleum products in Lagos metropolis ［J］.Environment international, 2002， 28(1/2): 79-82. ［22］ KUBOV，J MATUS P, BUJDOSM, et al.Utilization of optimized BCR threestep sequential and dilute HCl single extraction procedures for soil–plant metal transfer predictions in contaminated lands ［J］.Talanta, 2008, 75(4): 1110-1122. ［23］ MOSSOP K F, DAVIDSON C M.Comparison of original and modified BCR sequential extraction procedures for the fractionation of copper, iron, lead, manganese and zinc in soils and sediments ［J］.Analytica Chimica Acta, 2003, 478(1): 111-118. ［24］李亮亮, 张大庚, 李天来,等.土壤有效态重金属提取剂选择的研究 ① ［J］.土壤, 2008, 40(5): 819-823. ［25］李发生, 韩梅, 熊代群, 等.不同浸提剂对几种典型土壤中重金属有效态的浸提效率研究［J］.农业环境科学学报, 2003， 22(6): 704-706. ［26］ ZHONG X L, ZHOU S L, ZHU Q,et al.Fraction distribution and bioavailability of soil heavy metals in the Yangtze River Delta-A case study of Kunshan City in Jiangsu Province, China ［J］.Journal of hazardous materials, 2011， 198: 13-21. ［27］ RODRIGUEZ L，RUIZ E,ALONSOAZCARATEJ,et al.Heavy metal distribution and chemical speciation in tailings and soils around a PbZn mine in Spain ［J］.Journal of environmental management, 2009, 90(2): 1106-1116. ［28］ GB156181995,土壤环境质量标准［S］. ［29］国家环境保护局.中国土壤元素背景值［M］.北京：中国环境科学出版社,1990. ［30］ KAASALAINEN M, YLIHALLA M.Use of sequential extraction to assess metal partitioning in soils ［J］.Environmental Pollution, 2003, 126(2): 225-233. ［31］ NEMATI K, BAKAR N K A, ABAS M R.Investigation of heavy metals mobility in shrimp aquaculture sludgeComparison of two sequential extraction procedures ［J］.Microchemical Journal, 2009, 91(2): 227-231.

[1]	许冬宁, 吴晓青, 周方园, 范素素, 张新建, 肖桂青, 王加宁. 减少农田土壤氮损失的微生物调控技术研究进展[J]. 山东科学, 2024, 37(2): 117-126.
[2]	徐蕾, 赵汝松, 景传勇, 王霞. 环境介质中锑形态分析技术的研究进展[J]. 山东科学, 2023, 36(4): 122-133.
[3]	李玲玉, 黄璐琦, 李政, 王晓, 刘伟, 张华敏, 马春霞. 基于传统分离和高通量测序的健康和患锈腐病西洋参根际土壤微生物群落分析[J]. 山东科学, 2023, 36(2): 41-49.
[4]	扈进冬, 李红梅, 吴远征, 魏艳丽, 李纪顺. 四种蔬菜土壤真菌群落组成与多样性[J]. 山东科学, 2023, 36(1): 58-65.
[5]	王贻莲, 黄鼎立, 魏艳丽, 李红梅, 杨合同, 李纪顺. 土壤调理剂和木霉LTR-2联合施用对小油菜连作障碍土壤的修复[J]. 山东科学, 2022, 35(6): 74-79.
[6]	曹鑫磊, 姜浩, 杨宝山, 焦克芹, 王惠. 纳米银对小麦秸秆还田土壤中酶活性及微生物群落功能多样性的影响[J]. 山东科学, 2021, 34(3): 80-89.
[7]	侯广利, 李雪莹, 邱慧敏, 吕红敏, 刘钰祥, 范萍萍. 土壤磷形态的反射光谱特征及其光谱建模[J]. 山东科学, 2021, 34(1): 82-88.
[8]	张腾飞, 黄玉杰, 季蕾, 王加宁. 石油污染土壤生物修复技术研究进展[J]. 山东科学, 2020, 33(5): 106-112.
[9]	赵燕芳, 翟振国, 陈相峰. 波长散射-X射线荧光光谱法测定设施蔬菜集约区土壤中5种重金属[J]. 山东科学, 2019, 32(5): 131-135.
[10]	陈金旭, 马凯旋, 牟立同, 曹辉, 黄萍, 范伟国, 杨洪强, 张玮玮, 王利. 鸡粪添加木质素对平邑甜茶根区土壤硝酸盐代谢的影响[J]. 山东科学, 2019, 32(3): 73-79.
[11]	宋以玲, 马学文, 于建, 李巧玉, 孟庆羽, 丁方军. 复合微生物肥料替代部分复合肥对花生生长及根际土壤微生物和理化性质的影响[J]. 山东科学, 2019, 32(1): 38-45.
[12]	扈进冬, 吴远征, 魏艳丽, 李红梅, 辛相启, 杨凯, 李纪顺. 木霉拌种剂对小麦根际土壤真菌群落多样性的影响[J]. 山东科学, 2019, 32(1): 46-51.
[13]	陈凡. 非饱和土壤水流问题的半离散间断有限体积元方法[J]. 山东科学, 2018, 31(5): 95-100.
[14]	李三喜，马龙，吕京生，张发祥，刘小会,赵庆超，李惠,王昌 . 用于油井温度剖面快速测量的高精度光纤光栅温度传感器设计[J]. 山东科学, 2018, 31(3): 55-60.
[15]	陈士更，宋以玲，于建，肖承泽，李玉环，丁方军，张民. 玉米秸秆还田及腐熟剂对小麦产量、土壤微生物数量和酶活性的影响[J]. 山东科学, 2018, 31(2): 25-31.

胜利油田石油污染土壤中重金属的形态分析

Speciation analysis of heavy metals in oilpolluted soil of Shengli Oilfield

PDF (PC)

赞

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

本文评价

推荐阅读 0