环境介质中锑形态分析技术的研究进展

doi:10.3976/j.issn.1002-4026.2023.04.015

Abstract

Abstract:

This study reviews the speciation analysis methods of antimony indifferent environmental media in recent years. Inductively-coupled plasma mass spectrometry is widely used in the antimony speciation analysis because of its advantages such as low detection limit, high sensitivity, and good stability. Before the speciation analysis, extracting different forms of antimony from a complex matrix and maintaining its valence stability are essential. This can be achieved by combining the sensitive detection technology, efficient sample pretreatment techniques, and separation methods. In recent years, the combined techniques have been widely used for the determination of antimony in various environmental samples. Moreover, the challenges in this field and the development prospect of antimony speciation analysis method are discussed.

Key words: antimony, speciation analysis, pretreatment techniques, liquid chromatography, hyphenated technology, review

CLC Number:

X703

XU Lei, ZHAO Rusong, JING Chuanyong, WANG Xia. Review on the analytical technique for antimony speciation in environmental media[J].Shandong Science, 2023, 36(4): 122-133.

Figures/Tables 3

Table 1

Table 2

Table 3

Application of mass spectrometry in antimony speciation"

锑形态	分析方法	样品	萃取剂	分离条件	检出限	参考文献
Sb(III) Sb(V)	HPLC-ICP-MS	水	0.11 mol/L乙酸, pH=2.85 0.1 mol/L盐酸羟胺, pH=2.0 8.8 mol/L H₂O₂ +1.0 mol/L乙酸铵, pH=2.0	色谱柱: Dionex Ion Pac AS-7 (50 mm×4 mm, 10 μm) 柱温: 35 °C 流动相: 1.0 mmol/L邻苯二甲酸酯 +10 mmol/L EDTA, pH=4.5 流速: 1.2 mL/min	0.009 g/L 0.012 g/L	[69]
Sb(III) Sb(V)	HPLC-ICP-MS	水、沉积物	5 mmol/L Na₂HPO₄, 50 mmol/L KH₂PO₄ pH=6.0±0.2	色谱柱: Ion Pac AG-7 (50 mm×4 mm, 10 μm) 柱温: 35 ℃ 流动相:A: 0.1 mol/L NH₄NO₃, pH=4 B:0.8 mol/L HNO₃ 流速: 1.7 mL/min	0.009 μg/L 0.012 μg/L	[70]
Sb(III) Sb(V)	HPLC-ICP-MS	水、沉积物	0.11 mol/L乙酸 0.1 mol/L盐酸羟胺 8.8 mol/L H₂O₂ +1.0 mol/L乙酸铵	色谱柱: DionexIonPac AS 7 (250 mm×4 mm, 10 μm) 柱温: 30 ℃ 流动相: 1.5 mmol/L phthalate +10 mmol/L EDTA, pH=4.0 流速: 0.7 mL/min	0.009 μg/L 0.014 μg/L	[71]
Sb(III) Sb(V)	HPLC-ICP-MS	PM_2.5	0.04 mol/L盐酸羟胺 +10%乙酸+0.05 mol/L EDTA	色谱柱: Hamilton PRP-X100 (4.6 mm×150 mm, 5 μm) 流动相:0.03 mol/L NH₄NO₃ +0.001 mol/L EDTA, pH=3.5 流速: 1.0 mL/min	0.10 ng/m³ 0.06 ng/m³	[72]
Sb(III) Sb(V)	HPLC-ICP-MS	土壤	100 mmol/L柠檬酸	色谱柱: Hamilton PRP-X100 (25 cm×4.1 mm, 10 μm) 流动相: 200 mmol/L酒石酸铵 +4%甲醇, pH=5.0 流速: 1.2 mL/min	0.03 μg/L 0.02 μg/L	[73]
Sb(III) Sb(V)	ETV-ICP-MS	食品	6.0 mg TDNFs 15 μL三氯甲烷	载气流量:0.43 L/min 干燥温度: 100 ℃ 灰化温度: 200 ℃ 蒸发温度: 2 000 ℃ 清洗温度: 2 600 ℃	0.019 ng/L 0.025 ng/L	[74]
Sb(III)	IC-ICP-MS	水		色谱柱:Hamilton PRP-X100 (4.6 mm×250 mm) 流动相:10 mmol/L EDTA, 3 mmol/L EDTA 流速: 1.0 mL/min	0.003~0.004 μg/L	[75]
Sb(III) Sb(V)	IC-ICP-MS	水、食品		色谱柱: Hamilton PRP-X100 (250 mm×4 mm, 10 μm) 流动相: A: 20 mmol/L EDTA, 2 mmol/L KHP, 1%甲醇, pH=5.5 B: 20 mmol/L EDTA, 2 mmol/L KHP, 40 mmol/L (NH4)2CO3, 1%甲醇, pH=9.0 流速:1.2 mL/min	0.012~0.032 μg/L	[76]
Sb(III)	IC-ICP-MS	食品		色谱柱: Hamilton PRP-X100 (250 mm×4.6 mm) 流动相: 10 mmol/L EDTA +1 mmol/L邻苯二甲酸氢钾流速: 1.0 mL/min	0.1 μg/L	[77]

Table 3

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Review on the analytical technique for antimony speciation in environmental media

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锑形态	前处理方法	萃取剂	样品	检出限	参考文献
Sb(III)	SPE	APDC	水	2.1 ng/L	[35]
Sb(III)	SPE	TPA-SG	水	0.020 μg/L	[36]
Sb(III)	在线SPE	NPC pro-MWCNT	水	1.47 ng/L 0.52 ng/L	[37]
Sb(III) Sb(V)	在线SPE	SiO₂/Al₂O₃/SnO₂	水	0.17 μg/L	[38]
Sb(III)	MSPE	Fe₃O₄@SiO₂@CNFs	水	0.13 μg/L	[39]
Sb(III) Sb(V)	MSPE	C₈-Fe₃O₄@SiO₂	水	0.001 μg/L 0.004 μg/L	[40]
Sb(III)	SPME	Fe₃O₄@Ag@MESNa	水	0.02 μg/L	[41]
Sb(III)	SPME	POIP	水	6 ng/L	[42]
Sb(III)	CPE	Triton X-114	水	0.06 μg/L	[45]
Sb(III)	DLLME	[P_6,6,6,14]FeCl₄	水	0.02 μg/L	[46]
Sb(III)	VAME	DES	水、生物样品	5.6 ng/L	[47]
Sb(III) Sb(V)	DMSPE -DLLME	TDNFs, CHCl₃	生物样品	0.019 ng/L 0.025 ng/L	[43]
Sb(III) Sb(V)	微波萃取	0.1 mol/L草酸+20 mmol/L 抗坏血酸	土壤、沉积物	0.1 μg/L 0.2 μg/L	[44]

锑形态	分析方法		样品	萃取剂		分离条件	检出限			参考文献
Sb(III) Sb(V)	ET- AAS		水	Fe₃O₄@ Ag@MESNa		10%硝酸溶液1 mol/L, pH=9, 碳酸盐/碳酸氢盐缓冲溶液	0.02 μg/L			[41]
Sb(III)	ET- AAS		水	3.5%APDC+ 3.0%Triton X-114		3.0%L-半胱氨酸	0.06 μg/L			[43]
Sb(III)	HG-AAS		水、食品	DES		碳酸氢盐缓冲液, pH=10.5 3×10^-3mol/L H₂Dz 四氢呋喃(THF)	5.6 ng/L			[45]
Sb(III)	FIA-HG-AAS		水	SiO₂/Al₂O₃/SnO₂			0.17 μg/L			[38]
Sb(III)	FI-HG-AAS		水	A:pro-MWCNTs B:不同碳纳米材料			1.47μg/L 0.52 μg/L			[53]
Sb(V) Sb(III) + Sb(V)	GF-AAS		水	2-噻吩甲酰基三氟丙酮		1%硝酸镁与1%硝酸钯 (体积比1:1)混合基体改进剂	0.0678 μg/L 0.059 4 μg/L			[49]
Sb(III)	HG-AFS		水				9 ng/L			[54]
Sb(III) Sb(III) +Sb(V)	HG-AFS		食品	3.5 mol/L HCl		3.5 mol/L HCl_(aq) 10 g/L NaF_(aq) 50 g/L硫脲+50 g/L抗坏血酸混合物	0.15 μg/L 0.07 μg/L			[55]
Sb(III)	FBA-HG-AFS		水			10%柠檬酸钠 50%KI+10%抗坏血酸	6 ng/L			[57]
Sb(III) Sb(V)	MSFIA-HG-AFS		水	0.05% 8-羟基喹啉		50% KI	0.03 μg/L			[58]
Sb(III) Sb(V)	MSFIA-HG-AFS		土壤	8-羟基喹啉		50%KI+10%抗坏血酸	0.9 ng/g			[59]
Sb(III) Sb(V)	HPLC-HG-AFS		土壤	0.2 mol/L酒石酸溶液		色谱柱: DionexIonPac AS19 (250 mm×4 mm) 流动相: 1 mmol/L邻苯二甲酸氢钾+ 10 mmol/L EDTA 流速: 1.0 mL/min	0.010 μg/g 0.015 μg/g			[66]
Sb(III) Sb(V)	HPLC-HG-AFS	土壤、沉积物			0.1 mol/L草酸+ 20 mmol/L抗坏血酸	色谱柱: Hamilton PRP-×100 (100 mm×4.1 mm, 5 μm) 流动相: 20 mmol/L EDTA, pH=4.5 流速: 1.5 mL/min			[67]
Sb(III) Sb(V)	HPLC-HG-AFS	大气颗粒物			0.05 mol/L NH₂OH·HCl	色谱柱: Hamilton PRP-X100 (100 mm×4.1 mm, 10 μm) 流动相: 0.2 mol/L酒石酸二铵溶液, pH=5 流速: 0.8 mL/min			[60]
Sb(III)	ICP-OES	水			磁性离子印迹聚合物			0.13 μg/L	[65]
Sb(III)	ICP-OES	水			多离子印迹聚合物			0.011 μg/L	[68]

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