离子掺杂黄长石结构ABC3O7发光材料的研究进展

doi:10.3976/j.issn.1002-4026.2025128

Abstract

Abstract:

Melilite-structured compounds with the general formula ABC₃O₇—where A is an alkaline earth metal (e.g., Ca²⁺, Sr²⁺, or Ba²⁺), B is a trivalent rare-earth ion, and C is a trivalent main-group element (e.g., Ga³⁺ or Al³⁺)—represent an important class of inorganic functional materials. Owing to their stable crystal structure, tunable chemical composition, excellent physical and chemical stability, and multiple lattice sites available for activator ions, these materials have shown considerable potential in luminescence applications. This article provides a systematic review of recent advances in ion-doped ABC₃O₇-based luminescent materials. It highlights the characteristic features of the melilite-type crystal structure and presents a comprehensive summary of the luminescent properties, site occupancy behaviors, and concentration quenching effects of representative activator ions, including Eu³⁺, Tb³⁺, Dy³⁺, Mn²⁺, and Cr³⁺, within this host lattice. Additionally, the energy transfer mechanisms between sensitizers (e.g., Bi³⁺) and activator ions are thoroughly examined, and strategies for color tuning and performance enhancement via ion co-doping are discussed. Finally, current challenges and future research directions are outlined, providing theoretical insights and practical guidance for the rational design of high-performance melilite-structured luminescent materials.

Key words: melilite-structured compounds, luminescent materials, ion doping, energy transfer, performance regulation

CLC Number:

TB383

WANG Xuping, SHEN Xiaona, YANG Yuguo. Research advances in ion-doped melilite-structured ABC₃O₇ luminescent materials[J].Shandong Science, 2026, 39(2): 74-88.

Figures/Tables 10

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Table 1

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基质材料	掺杂离子	激发波长/nm	发射波长/nm	宽带范围/nm	参考文献
BaLaGa₃O₇	Bi³⁺	470	328	360~650	[36]
BaLaGa₃O₇	Bi³⁺/Eu³⁺	480	335	370~710	[37]
CaLaGa₃O₇	Dy³⁺	573	349	400~650	[38]
CaLaGa₃O₇	Dy³⁺/Tm³⁺	573	355	350~650	[39]
SrLaGa₃O₇	Bi³⁺	475	365	350~650	[40]
	Bi³⁺/Mn⁴⁺	714	365	350~750	[40]
	Eu³⁺	615	392	550~750	[41]
	Tb³⁺	546	265	450~650	[42]
	Er³⁺/Yb³⁺	900	378	500~700	[42]
	Cr³⁺	1167	450	950~1 500	[43]
	Cr⁴⁺	1270	610	950~1 600	[43]
SrGdGa₃O₇	Tb³⁺	543	235	350~650	[44]
CaYAl₃O₇	Dy³⁺	574	350	400~650	[45]
	Gd³⁺	313	272	290~340	[46]
	Cr⁴⁺	1360	565	900~1 850	[47]
	Cr³⁺	875	425	750~1 250	[47]
CaLaAl₃O₇	Ho³⁺/Yb³⁺	547	450	450~800	[48]
	Tm³⁺/Yb³⁺	650	462	450~800	[49]
	Er³⁺/Yb³⁺	549	450	500~700	[50]
CaGdAl₃O₇	Tm³⁺/Yb³⁺/Zn²⁺	980	475	350~900	[51]
SrGdAl₃O₇	Er³⁺/Yb³⁺	980	550	500~700	[52]

Research advances in ion-doped melilite-structured ABC₃O₇ luminescent materials

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Research advances in ion-doped melilite-structured ABC3O7 luminescent materials

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Research advances in ion-doped melilite-structured ABC₃O₇ luminescent materials