Environment-friendly high-efficiency CH3NH3PbI3 perovskite solar cells fabrication based on green antisolvent method
MENG Jinga(), GAO Bowenb,*()
a. Network and Educational Technology Center, Taishan University, Tai'an 271021,China b. Institute of Photovoltaic Materials and Building Integration, School of Mechanical and Civil Engineering, Taishan University, Tai'an 271021,China
MENG Jing, GAO Bowen. Environment-friendly high-efficiency CH3NH3PbI3 perovskite solar cells fabrication based on green antisolvent method[J].Shandong Science, 2023, 36(3): 46-52.
CH3NH3PbI3 perovskite films fabricated using green antisolvent method"
Fig.1
Fig.2
Scanning electron microscopy images of perovskite films with different antisolvents"
Fig.2
Table 1
Perovskite films with different antisolvents and corresponding device parameters"
反溶剂处理
粒径/nm
表面粗糙度/nm
串联电阻/(Ω·cm2)
并联电阻/(Ω·cm2)
丙二醇甲醚
500
12
50
2 000
乙酸丙酯
430
20
150
1 500
氯苯
360
25
300
1 200
参照系
250
30
1 000
300
Table 1
Fig.3
Absorption spectra and XRD patterns of CH3NH3PbI3 perovskite films treated with different antisolvents"
Fig.3
Fig.4
Photovoltaic performance of CH3NH3PbI3 perovskite-type solar cells prepared by adding different antisolvents and hysteresis characteristics of perovskite-type solar cells treated with propylene glycol methyl ether"
Fig.4
Table 2
Photovoltaic performance parameters of perovskite-type devices prepared by adding different antisolvents"
KOJIMA A, TESHIMA K, SHIRAI Y, et al. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells[J]. Journal of the American Chemical Society, 2009, 131(17): 6050-6056. DOI: 10.1021/ja809598r.
doi: 10.1021/ja809598r
pmid: 19366264
[2]
NREL Best Research-Cell Efficiencies, Retrieved September 12, 2022[EB/OL].[2022-07-08]. https://www.nrel.gov/pv/assets/images/efficiency-chart.png.
[3]
DOMANSKI K, ALHARBI E A, HAGFELDT A, et al. Systematic investigation of the impact of operation conditions on the degradationbehaviour of perovskite solar cells[J]. Nature Energy, 2018, 3(1): 61-67. DOI: 10.1038/s41560-017-0060-5.
doi: 10.1038/s41560-017-0060-5
[4]
LIU Z F, KRÜCKEMEIER L, KROGMEIER B, et al. Open-circuit voltages exceeding 1.26 V in planarmethylammonium lead iodide perovskite solar cells[J]. ACS Energy Letters, 2019, 4(1): 110-117. DOI: 10.1021/acsenergylett.8b01906.
doi: 10.1021/acsenergylett.8b01906
GAO B W, MENG J. Highly stable all-inorganic CsPbIBr2 perovskite solar cells with 11.30% efficiency using crystal interfacepassivation[J]. ACS Applied Energy Materials, 2020, 3(9): 8249-8256. DOI: 10.1021/acsaem.0c00678.
doi: 10.1021/acsaem.0c00678
[7]
GAO B W, MENG J. RbCs(MAFA)PbI3 perovskite solar cell with 22.81% efficiency using the precise ions cascade regulation[J]. Applied Surface Science, 2020, 530: 147240. DOI: 10.1016/j.apsusc.2020.147240.
doi: 10.1016/j.apsusc.2020.147240
[8]
LIU KK, LUO Y J, JIN Y B, et al. Moisture-triggered fast crystallization enables efficient and stable perovskite solar cells[J]. Nature Communications, 2022, 13(1): 1-10. DOI: 10.1038/s41467-022-32482-y.
doi: 10.1038/s41467-022-32482-y
[9]
LIANG Y M, SONG P Q, TIAN H R, et al. Lead leakage preventable fullerene-porphyrin dyad for efficient and stable perovskite solarcells[J]. Advanced Functional Materials, 2022, 32(14): 2110139. DOI: 10.1002/adfm.202110139.
doi: 10.1002/adfm.202110139
[10]
CAO Q, WANG T, YANG J B, et al. Environmental-friendly polymer for efficient and stable inverted perovskite solar cells with mitigating lead leakage[J]. Advanced Functional Materials, 2022, 32(32): 2201036. DOI: 10.1002/adfm.202201036.
doi: 10.1002/adfm.202201036