NHPI/MnSO4催化氧化对硝基甲苯制对硝基苯甲酸

J4 ›› 2011, Vol. 24 ›› Issue (3): 18-21.

NHPI/MnSO₄催化氧化对硝基甲苯制对硝基苯甲酸

郑立稳, 陈贯虹, 孔学, 邱维忠, 迟建国, 王加宁

山东省科学院生物研究所，山东省应用微生物重点实验室，山东济南 250014

收稿日期:2010-12-29 出版日期:2011-06-20 发布日期:2011-06-20
作者简介:郑立稳（1981-），男，硕士，主要从事有机合成及农药创制

NHPI/MnSO₄ catalyzed oxidation of p-Nitrotoluene to p-Nitrobenzoic acid

ZHENG Li-Wen, CHEN Guan-Hong, KONG Xue, QIU Wei-Zhong, CHI Jian-Guo, WANG Jia-Ning

Shandong Provincial Key Laboratory of Applied Microbiology, Institute of Biology, Shandong Academy of Sciences, Jinan 250014, China

Received:2010-12-29 Online:2011-06-20 Published:2011-06-20

摘要/Abstract

摘要：

本文报道了以N 羟基邻苯二甲酸亚胺（NHPI）/MnSO₄为催化剂，冰乙酸为溶剂，氧气为氧化剂，催化氧化对硝基甲苯制对硝基苯甲酸，并对反应条件进行了研究，对硝基甲苯的转化率和对硝基苯甲酸的产率分别达到91.3%和82.5%，应用前景较好。

关键词: NHPI, 催化氧化, 对硝基甲苯, 对硝基苯甲酸

Abstract:

This paper presented NHPI/MnSO₄ catalyzed oxidation of p-Nitrotoluene to p-Nitrobenzoic acid with glacial acetic acid as solvent and oxygen as an oxidant. We optimized the reaction conditions for this chemical reaction. The conversion rate of p-Nitrotoluene and the production rate of p-Nitrobenzoic acid reached 91.3% and 82.5% under these optimum conditions, so this catalytic reaction has better application prospect.

Key words: hydroxyphthalimide (NHPI), catalytic oxidation, p-Nitrotoluene, p-Nitrobenzoic acid

中图分类号:

O625.61

郑立稳, 陈贯虹, 孔学, 邱维忠, 迟建国, 王加宁. NHPI/MnSO₄催化氧化对硝基甲苯制对硝基苯甲酸[J]. J4, 2011, 24(3): 18-21.

ZHENG Li-Wen, CHEN Guan-Hong, KONG Xue, QIU Wei-Zhong, CHI Jian-Guo, WANG Jia-Ning. NHPI/MnSO₄ catalyzed oxidation of p-Nitrotoluene to p-Nitrobenzoic acid[J]. J4, 2011, 24(3): 18-21.

NHPI/MnSO₄催化氧化对硝基甲苯制对硝基苯甲酸

NHPI/MnSO₄ catalyzed oxidation of p-Nitrotoluene to p-Nitrobenzoic acid

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