膨胀石墨负载二氧化钛改善亲水性的研究

doi:10.3976/j.issn.1002-4026.2019.01.010

山东科学 ›› 2019, Vol. 32 ›› Issue (1): 68-75.doi: 10.3976/j.issn.1002-4026.2019.01.010

膨胀石墨负载二氧化钛改善亲水性的研究

滕东晓1，陈文亮1，马元1，苏营雪1，那平2

1.淄博高新区精细化工和高分子材料研究院，山东淄博 255000; 2.天津大学，天津 300072

收稿日期:2018-08-18 出版日期:2019-02-20 发布日期:2019-01-25
作者简介:滕东晓（1990—），男，硕士研究生，研究方向为亲油疏水材料。E-mail: 245950221@qq.com
基金资助:
国家重点研发计划重点专项 (2016YFC1402400)

Research on the improvement of hydrophilicity by expanded graphite loaded titanium dioxide

TENG Dong-xiao¹,CHEN Wen-liang¹,MA Yuan¹,SU Ying-xue¹，NA Ping²

1.Fine Chemical & Polymer Materials China Institute of Zibo National New & Hi-tech Industrial Development Zone, Zibo 255000，China；2.Tianjin University, Tianjin 300072，China

Received:2018-08-18 Online:2019-02-20 Published:2019-01-25

摘要/Abstract

摘要： 以可膨胀石墨为原材料制备了表面负载有纳米级二氧化钛颗粒的载钛膨胀石墨，并对其微观形貌、接触角、孔径分布、孔容积、吸附能力进行了分析和表征。优化了膨胀石墨负载二氧化钛工艺，在负载温度50 ℃、钛柱撑液体积分数10%、反应时间6 h时，制备的载钛膨胀石墨亲水性最优。二氧化钛的引入使膨胀石墨接触角由93.0°降低至69.6°左右，亲水性能提高，增强了对水体中溶解或悬浮的微量苯系物的吸附能力。

关键词: 膨胀石墨, 负载, 二氧化钛, 吸附性能

Abstract: The expanded graphite coated with nano-TiO₂ particles was prepared from expandable graphite as raw material. The micro-morphology, contact angle, pore size distribution, pore volume and adsorption capacity were analyzed and characterized. The process of titanium dioxide supported on expanded graphite was optimized. The hydrophilicity of the prepared expanded graphite was the best when the loading temperature was 50 degrees Celsius, the titanium pillared liquid volume fraction was 10%, and the reaction time was 6 h. With the introduction of titanium dioxide, the contact angle of expanded graphite was reduced from 93.0°to about 69.6°, and the hydrophilic property was improved. The adsorption capacity of benzene homologues which was dissolved or suspended in water was enhanced.

Key words: expanded graphite, load, titanium dioxide, adsorption properties

中图分类号:

TQ53

滕东晓, 陈文亮, 马元, 苏营雪, 那平. 膨胀石墨负载二氧化钛改善亲水性的研究[J]. 山东科学, 2019, 32(1): 68-75.

TENG Dong-xiao, CHEN Wen-liang, MA Yuan, SU Ying-xue, NA Ping. Research on the improvement of hydrophilicity by expanded graphite loaded titanium dioxide[J]. Shandong Science, 2019, 32(1): 68-75.

[1]	谭双美, 关迎东, 赵帅, 李琳. 高耐磨导静电石墨烯杂化材料/丁苯/顺丁胎面胶的研制[J]. 山东科学, 2024, 37(2): 55-64.
[2]	陈凌霄，马秀丽，王晓，耿岩玲，高乾善，谢宏凯，纪文华. 天麻素分子印迹聚合物的吸附和识别性能研究[J]. J4, 2014, 27(3): 17-22.
[3]	王秀芬, 张曙伟, 吕斌, 吴承璇, 曲君乐. PIC单片机控制的漏电保护器测试系统[J]. J4, 2011, 24(2): 81-83.

膨胀石墨负载二氧化钛改善亲水性的研究

Research on the improvement of hydrophilicity by expanded graphite loaded titanium dioxide

PDF (PC)

赞

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 3

Metrics

本文评价

推荐阅读 0