加速溶剂萃取-GPC纯化-气相色谱-质谱法测定油区土壤中的16种多环芳烃

doi:10.3976/j.issn.1002-4026.2015.02.014

山东科学 ›› 2015, Vol. 28 ›› Issue (2): 81-86.doi: 10.3976/j.issn.1002-4026.2015.02.014

加速溶剂萃取-GPC纯化-气相色谱-质谱法测定油区土壤中的16种多环芳烃

王磊磊，郑立稳，孔学，陈贯虹，王加宁

山东省科学院生物研究所，山东济南 250014

收稿日期:2015-02-04 出版日期:2015-04-20 发布日期:2015-04-20
作者简介:王磊磊(1986-)，男，博士，研究方向为有机合成与有机分析。Email: heat_33wll@163.com
基金资助:
山东省科学院先导科技专项（2013）；山东省科技发展计划项目（2013GSF11703)

Determination of 16 PAHs in oil field soil samples with accelerated solventextraction, GPC and gas chromatographymass spectrometry

WANG Lei-lei, ZHENG Li-wen, KONG Xue, CHEN Guan-hong, WANG Jia-ning

Biology Institute, Shandong Academy of Sciences, Jinan 250014, China

Received:2015-02-04 Online:2015-04-20 Published:2015-04-20

摘要/Abstract

摘要： 为了排除背景干扰，使测定数据更加准确，先通过加速溶剂萃取和GPC纯化方法富集油区土壤中约16种多环芳烃, 再借助于气相色谱质谱建立了高效、准确的分析方法。该方法对16种多环芳烃的相关系数在0.997以上，检出限为0.8~7.3 ng/mL，回收率为82.8％~94.2％，相对标准偏差为1.38％~8.86％。对实际样品的分析检测结果表明，本方法在油区土壤中的多环芳烃分析方面值得推广。

关键词: 加速溶剂萃取, 油区土壤, 多环芳烃, 气相色谱-质谱法, GPC

Abstract: We collected 16 PAHs in oil field soil samples with accelerated solvent extraction and GPC to eliminate background interference and make acquired data more reliable.We then constructed efficient and precise analysis method by gas chromatographymass spectrometry.Its correlation coefficients with 16 polycyclic aromatic hydrocarbons were more than 0.997. Its detection limit, average recovery rate and RSD were 0.8~7.3 ng/mL, 82.8％~94.2％, and 1.38％~8.86％.Practical analysis and test results show that the method was suitable for PAHs analysis of oil field soil.

Key words: GPC, polycyclic aromatic hydrocarbon (PAHs), oil field soil, accelerated solvent extraction, GC/MS

中图分类号:

X502

王磊磊，郑立稳，孔学，陈贯虹，王加宁. 加速溶剂萃取-GPC纯化-气相色谱-质谱法测定油区土壤中的16种多环芳烃[J]. 山东科学, 2015, 28(2): 81-86.

WANG Leilei, ZHENG Liwen, KONG Xue, CHEN Guanhong, WANG Jianing. Determination of 16 PAHs in oil field soil samples with accelerated solventextraction, GPC and gas chromatographymass spectrometry[J]. SHANDONG SCIENCE, 2015, 28(2): 81-86.

参考文献

［1］NORDING M,FRECH K,PERSSON Y, et al. On the semiquantification of polycyclic aromatic hydrocarbons in contaminated soil by an enzymelinked immunosorbent assay kit ［J］. Anal Chim Acta, 2006, 555（1）: 107-113. ［2］BARCOBONILLA N, VIDAL J L M, FRENICH A G, et al. Comparison of ultrasonic and pressurized liquid extraction for the analysis of polycyclic aromatic compounds in soil samples by gas chromatography coupled to tandem mass spectrometry ［J］. Talanta, 2009, 78（1）: 156-164. ［3］匡少平, 孙东亚. 多环芳烃的毒理学特征与生物标记物研究［J］. 世界科技研究与发展, 2007, 29 (2): 41-47. ［4］孙剑英，刘五星，骆永明，等.气象色谱-质谱法测定含油污泥污染土壤中的多环芳烃［J］.土壤, 2013, 45(1):111-115. ［5］张明亮，黎慧，徐英江，等. 莱州湾表层沉积物中多环芳烃(PAHs)来源及生态风险评价［J］.海洋环境科化学, 2015,31(1):6–11. ［6］李斌，刘昕宇，解启来，等. 自动索氏提取凝胶渗透色谱(GPC)气相色谱/质谱法测定沉积物中多环芳烃和有机氯农药［J］. 环境化学, 2014, 33(2): 236–242. ［7］谢莹，张涛，魏薇，等. 超声提取气相色谱质谱法测定水体沉积物中16种多环芳烃［J］. 理化检验:化学分册, 2013, 49: 211–215. ［8］褚亮亮，薛文平，徐恒振，等. 超声提取液相色谱测定环境固体中多环芳烃［J］.大连工业大学学报, 2009, 28(6):448–451. ［9］林琳，王海，缪丽娜，等.微波提取高效液相色谱法测定土壤中15种痕量多环芳烃［J］. 中国环境监测, 2009, 25(2):86–89. ［10］徐建玲，盛连喜，王汉席，等.石油废物处置场周边土壤中多环芳烃的测定和评价［J］. 分析化学, 2014, 42(10): 1513–1517. ［11］王新成，赵金，赵汝松，等. 加速溶剂提取气质联用分析土壤中的多环芳烃［J］. 中国环境监测, 2014, 30(3): 144–148. ［12］王娜. 加速溶剂萃取固相萃取净化色谱法测定土壤中的多环芳烃和有机氯［J］. 环境化学, 2013, 32(3):524–525.

加速溶剂萃取-GPC纯化-气相色谱-质谱法测定油区土壤中的16种多环芳烃

Determination of 16 PAHs in oil field soil samples with accelerated solventextraction, GPC and gas chromatographymass spectrometry

PDF (PC)

赞

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 1

Metrics

本文评价

推荐阅读 0