离子掺杂黄长石结构ABC3O7发光材料的研究进展

doi:10.3976/j.issn.1002-4026.2025128

摘要/Abstract

摘要：

黄长石结构化合物,其通式为ABC₃O₇(其中A为碱土金属Ca²⁺、Sr²⁺、Ba²⁺;B为三价稀土离子RE³⁺;C为三价主族元素Ga³⁺或Al³⁺),是一类重要的无机功能材料。该类材料以其稳定的晶体结构、可调的组分、优良的物理化学稳定性以及为激活离子提供的多样化晶格位点,在发光材料领域展现出巨大的潜力。本文系统综述了近年来离子掺杂黄长石结构ABC₃O₇基质发光材料的研究进展。重点阐述了其典型的黄长石晶体结构特征,详细归纳了以Eu³⁺、Tb³⁺、Dy³⁺、Mn²⁺、Cr³⁺等为代表的激活离子在该类基质中的发光特性、格位占据行为以及浓度猝灭效应。深入探讨了Bi³⁺等敏化剂与激活离子之间的能量传递机理,并总结了通过离子共掺杂实现发光颜色调控和性能优化的策略。最后,对该领域当前面临的挑战和未来的研究方向进行了展望,旨在为设计高性能新型黄长石结构发光材料提供理论依据和实践指导。

关键词: 黄长石结构化合物, 发光材料, 离子掺杂, 能量传递, 性能调控

Abstract:

Melilite-structured compounds with the general formula ABC₃O₇—where A is an alkaline earth metal (e.g., Ca²⁺, Sr²⁺, or Ba²⁺), B is a trivalent rare-earth ion, and C is a trivalent main-group element (e.g., Ga³⁺ or Al³⁺)—represent an important class of inorganic functional materials. Owing to their stable crystal structure, tunable chemical composition, excellent physical and chemical stability, and multiple lattice sites available for activator ions, these materials have shown considerable potential in luminescence applications. This article provides a systematic review of recent advances in ion-doped ABC₃O₇-based luminescent materials. It highlights the characteristic features of the melilite-type crystal structure and presents a comprehensive summary of the luminescent properties, site occupancy behaviors, and concentration quenching effects of representative activator ions, including Eu³⁺, Tb³⁺, Dy³⁺, Mn²⁺, and Cr³⁺, within this host lattice. Additionally, the energy transfer mechanisms between sensitizers (e.g., Bi³⁺) and activator ions are thoroughly examined, and strategies for color tuning and performance enhancement via ion co-doping are discussed. Finally, current challenges and future research directions are outlined, providing theoretical insights and practical guidance for the rational design of high-performance melilite-structured luminescent materials.

Key words: melilite-structured compounds, luminescent materials, ion doping, energy transfer, performance regulation

中图分类号:

TB383

王旭平, 沈晓娜, 杨玉国. 离子掺杂黄长石结构ABC₃O₇发光材料的研究进展[J]. 山东科学, 2026, 39(2): 74-88.

WANG Xuping, SHEN Xiaona, YANG Yuguo. Research advances in ion-doped melilite-structured ABC₃O₇ luminescent materials[J]. Shandong Science, 2026, 39(2): 74-88.

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基质材料	掺杂离子	激发波长/nm	发射波长/nm	宽带范围/nm	参考文献
BaLaGa₃O₇	Bi³⁺	470	328	360~650	[36]
BaLaGa₃O₇	Bi³⁺/Eu³⁺	480	335	370~710	[37]
CaLaGa₃O₇	Dy³⁺	573	349	400~650	[38]
CaLaGa₃O₇	Dy³⁺/Tm³⁺	573	355	350~650	[39]
SrLaGa₃O₇	Bi³⁺	475	365	350~650	[40]
	Bi³⁺/Mn⁴⁺	714	365	350~750	[40]
	Eu³⁺	615	392	550~750	[41]
	Tb³⁺	546	265	450~650	[42]
	Er³⁺/Yb³⁺	900	378	500~700	[42]
	Cr³⁺	1167	450	950~1 500	[43]
	Cr⁴⁺	1270	610	950~1 600	[43]
SrGdGa₃O₇	Tb³⁺	543	235	350~650	[44]
CaYAl₃O₇	Dy³⁺	574	350	400~650	[45]
	Gd³⁺	313	272	290~340	[46]
	Cr⁴⁺	1360	565	900~1 850	[47]
	Cr³⁺	875	425	750~1 250	[47]
CaLaAl₃O₇	Ho³⁺/Yb³⁺	547	450	450~800	[48]
	Tm³⁺/Yb³⁺	650	462	450~800	[49]
	Er³⁺/Yb³⁺	549	450	500~700	[50]
CaGdAl₃O₇	Tm³⁺/Yb³⁺/Zn²⁺	980	475	350~900	[51]
SrGdAl₃O₇	Er³⁺/Yb³⁺	980	550	500~700	[52]

离子掺杂黄长石结构ABC₃O₇发光材料的研究进展

Research advances in ion-doped melilite-structured ABC₃O₇ luminescent materials

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