生物医用ZTM630镁合金微弧氧化表面改性研究

doi:10.3976/j.issn.1002-4026.2020.06.009

山东科学 ›› 2020, Vol. 33 ›› Issue (6): 64-71.doi: 10.3976/j.issn.1002-4026.2020.06.009

生物医用ZTM630镁合金微弧氧化表面改性研究

王世芳，李航，刘洪涛，马百常，周吉学，李涛*

齐鲁工业大学（山东省科学院），山东省科学院新材料研究所，山东省轻质高强金属材料省级重点实验室，山东济南 250014

收稿日期:2020-04-21 出版日期:2020-12-09 发布日期:2020-12-10
通信作者: 李涛，男，助理研究员，研究方向为轻合金。Tel:0531-88728308,E-mail: litao@sdas.org E-mail: wangshf@sdas.org
作者简介:王世芳（1990—），女，硕士，研究实习员，研究方向为金属腐蚀防护。E-mail: wangshf@sdas.org
基金资助:
国家重点研发计划(2017YFB0103904，2016YFB0301105)；山东省重点研发计划(2017CXGC0404)；济南市“高校20条”资助项目(2019GXRC030)；山东省科学院青年科学基金（2018QN0034）

Surface modification of ZTM630 magnesium alloy by micro-arc oxidation

WANG Shi-fang，LI Hang，LIU Hong-tao，MA Bai-chang，ZHOU Ji-xue，LI Tao*

Shandong Key Laboratory of High Strength Lightweight Metallic Materials, Advanced Materials Institute, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250014, China

Received:2020-04-21 Online:2020-12-09 Published:2020-12-10

摘要/Abstract

摘要： 为了进一步优化生物医用镁合金的耐蚀性能，满足临床使用要求，对新型生物医用高强韧ZTM630镁合金进行了微弧氧化表面改性处理。分别制备了氧化时间为2、5、8和15 min的微弧氧化试样，并对其组织结构和耐腐蚀性能进行了表征和分析。结果发现：随着氧化时间的延长，涂层厚度与表面粗糙度均呈现增高的趋势；当氧化时间为5 min时，试样表现出最强的耐蚀性。研究表明，微弧氧化时间的合理调控对于生物医用镁合金耐蚀性的提高具有重要的意义。

关键词: 镁合金, 微弧氧化, 生物医用, 耐蚀性, 涂层

Abstract: To further optimize the corrosion resistance of biomedical magnesium alloys and meet clinical use requirements, surface modification was performed on a novel biomedical ZTM630 magnesium alloy with high strength and toughness via micro-arc oxidation. Micro-arc oxidized samples with oxidation times of 2, 5, 8, and 15 min were prepared, and their microstructure and corrosion resistance were characterized and analyzed. Results show that coating thickness and surface roughness increased with the extension of oxidation time. However, the samples showed the highest corrosion resistance when oxidation time was 5 min. This study shows that the reasonable regulation of micro-arc oxidation time is of great significance in the improvement of corrosion resistance of the biomedical magnesium alloy.

Key words: magnesium alloy, micro-arc oxidation; biomedical, corrosion resistance, coating

中图分类号:

TG146.2

王世芳, 李航, 刘洪涛, 马百常, 周吉学, 李涛. 生物医用ZTM630镁合金微弧氧化表面改性研究[J]. 山东科学, 2020, 33(6): 64-71.

WANG Shi-fang, LI Hang, LIU Hong-tao, MA Bai-chang, ZHOU Ji-xue, LI Tao. Surface modification of ZTM630 magnesium alloy by micro-arc oxidation[J]. Shandong Science, 2020, 33(6): 64-71.

参考文献 28

1	ZHENG Y F, GU X N, WITTE F. Biodegradable metals[J]. Materials Science and Engineering R, 2014, 77: 1-34. doi: 10.1016/j.mser.2014.01.001
2	BOMMALA V K, KRISHNA M G, RAO C T. Magnesium matrix composites for biomedical applications: a review[J]. Journal of Magnesium and Alloys, 2019, 7(1): 72-79. doi: 10.1016/j.jma.2018.11.001
3	HAUDE M, INCE H, ABIZAID A, et al. Safety and performance of the second-generation drug-eluting absorbable metal scaffold in patients with de-novo coronary artery lesions (BIOSOLVE-II): 6 month results of a prospective, multicentre, non-randomised, first-in-man trial[J]. The Lancet, 2016, 387(10013): 31-39. doi: 10.1016/S0140-6736(15)00447-X
4	LEE J W, HAN H S, HAN K J, et al. Long-term clinical study and multiscale analysis of in vivo biodegradation mechanism of Mg alloy[J]. Proceedings of the National Academy of Sciences of the United States of America, 2016, 113(3): 716-721. doi: 10.1073/pnas.1518238113
5	ZHAO D W, HUANG S B, LU F Q, et al. Vascularized bone grafting fixed by biodegradable magnesium screw for treating osteonecrosis of the femoral head[J]. Biomaterials, 2016, 81: 84-92. doi: 10.1016/j.biomaterials.2015.11.038
6	LI T, HE Y, WU J H, et al. Effects of scandium addition on the in vitro degradation behavior of biodegradable Mg-1.5Zn-0.6Zr alloy[J]. Journal of Materials Science, 2018, 53(20): 14075-14086. doi: 10.1007/s10853-018-2626-4
7	LI T, HE Y, ZHOU J X, et al. Microstructure and mechanical property of biodegradable Mg-1.5Zn-0.6Zr alloy with varying contents of scandium[J]. Materials Letters, 2018, 229: 60-63. doi: 10.1016/j.matlet.2018.06.097
8	LIU Y, ZHENG Y F, CHEN X, et al. Fundamental theory of biodegradable metals:definition, criteria, and design[J]. Advanced Functional Materials, 2019, 29(18): 1805402. doi: 10.1002/adfm.201805402
9	孙翠翠, 周吉学, 赵东清, 等. Sn对镁及镁合金显微组织和性能影响的研究现状及展望[J]. 材料导报, 2017, 31(19): 60-65. doi: 10.11896/j.issn.1005-023X.2017.019.008
10	王胜强, 宋杰, 张泽平, 等. 生物降解Mg-Zn-Ca-Sn合金铸态组织和力学性能研究[J]. 金属功能材料, 2019, 26(1): 44-47.
11	郎海洋. 生物医用可降解Zn-Sn系和Zn-Mg-Sn系合金的制备、组织及性能研究[D]. 桂林: 桂林理工大学, 2019.
12	GU X N, ZHENG Y F, CHENG Y, et al. In vitro corrosion and biocompatibility of binary magnesium alloys[J]. Biomaterials, 2009, 30(4): 484-498. doi: 10.1016/j.biomaterials.2008.10.021
13	刘西伟. Mg-3Sn-0.5Mn合金的降解行为及生物相容性[D]. 哈尔滨: 哈尔滨工程大学, 2013.
14	曾荣昌, 崔蓝月, 柯伟. 医用镁合金:成分、组织及腐蚀[J]. 金属学报, 2018, 54(9): 1215-1235.
15	ZHANG E L,YIN D S,XU L P,et al.Microstructure,mechanical and corrosion properties and biocompatibility of Mg-Zn-Mn alloys for biomedical application[J]. Materials Science and Engineering: C, 2009, 29(3):987-993. doi: 10.1016/j.msec.2008.08.024
16	马百常, 周吉学, 王金伟, 等. 铸造Mg-6Zn-3Sn-0.5Mn镁合金组织和力学性能[J]. 铸造技术, 2018, 39(2): 263-266.
17	王娜娜, 周吉学, 刘玉, 等. ZTM630镁合金双级时效实验研究[J]. 山东科学, 2018, 31(3): 34-38. DOI: 10.3976/j.issn.1002-4026.2018.03.006.
18	马百常. 高性能Mg-Zn-Sn-Mn挤压镁合金组织与力学性能研究[D]. 济南: 山东建筑大学, 2016.
19	李涛, 张海龙, 何勇, 等. 生物医用镁合金研究进展[J]. 功能材料, 2013, 44(20): 2913-2918. doi: 10.3969/j.issn.1001-9731.2013.20.002
20	HORNBERGER H, VIRTANEN S, BOCCACCINI A R. Biomedical coatings on magnesium alloysa review[J]. Acta Biomaterialia, 2012, 8(7): 2442-2455. doi: 10.1016/j.actbio.2012.04.012
21	YIN Z Z, QI W C, ZENG R C, et al. Advances in coatings on biodegradable magnesium alloys[J]. Journal of Magnesium and Alloys, 2020, 8(1): 42-65. doi: 10.1016/j.jma.2019.09.008
22	SANKARA NARAYANAN T S N, PARK I S, LEE M. Strategies to improve the corrosion resistance of microarc oxidation (MAO) coated magnesium alloys for degradable implants: prospects and challenges[J]. Progress in Materials Science, 2014, 60: 1-71. doi: 10.1016/j.pmatsci.2013.08.002
23	ZHANG Z Q, WANG L, ZENG M Q, et al. Biodegradation behavior of micro-arc oxidation coating on magnesium alloy-from a protein perspective[J]. Bioactive Materials, 2020, 5(2): 398-409. DOI:. doi: 10.1016/j.bioactmat.2020.03.005
24	HAN L Y, LI X, XUE F, et al. Biocorrosion behavior of micro-arc-oxidized AZ31 magnesium alloy in different simulated dynamic physiological environments[J]. Surface and Coatings Technology, 2019, 361: 240-248. doi: 10.1016/j.surfcoat.2019.01.052
25	WANG Y S, LI X, CHEN M F, et al. In vitro and in vivo degradation behavior and biocompatibility evaluation of microarc oxidation-fluoridated hydroxyapatite-coated Mg-Zn-Zr-Sr alloy for bone application[J]. ACS Biomaterials Science and Engineering, 2019, 5(6): 2858-2876. doi: 10.1021/acsbiomaterials.9b00564
26	国家质量技术监督局. 色漆和清漆漆膜的划格试验:GB/T 9286—1998[S]. 北京: 中国标准出版社, 1999.
27	王艳秋, 吴昆, 王福会. 第二相对镁基材料微弧氧化过程的影响机制[J]. 金属学报, 2016, 52(6): 689-697. doi: 10.11900/0412.1961.2015.00500
28	GUNDUZ K O, OTER Z C, TARAKCI M, et al. Plasma electrolytic oxidation of binary Mg-Al and Mg-Zn alloys[J]. Surface and Coatings Technology, 2017, 323: 72-81. doi: 10.1016/j.surfcoat.2016.08.040

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生物医用ZTM630镁合金微弧氧化表面改性研究

Surface modification of ZTM630 magnesium alloy by micro-arc oxidation

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