山东科学 ›› 2016, Vol. 29 ›› Issue (6): 74-79.doi: 10.3976/j.issn.1002-4026.2016.06.012

• 生物质能源 • 上一篇    下一篇

超低温预处理对椰壳基活性炭物理特性的影响

司洪宇1,杨黎军2,孙坤元1,梁晓辉1,赵玉晓1,张晓东1*,张元成3   

  1. 1.山东省科学院能源研究所, 山东 济南 250014,2.山东冠宝林炭业集团有限公司,山东 青岛 266300, 3.山东宝力生物质能源股份有限公司,山东 东营 257000
  • 收稿日期:2016-06-24 出版日期:2016-12-20 发布日期:2016-12-20
  • 作者简介:司洪宇(1980—),男,助理研究员,研究方向为生物质热化学转化。
  • 基金资助:

    国家科技支撑计划(2015BAD21B01);公益性行业(农业)科研专项(201503135-04);山东省重点研发计划(2015GSF117034);青海省科技促进新农村计划项目(2013-N-547)

Impact of ultralow temperature pretreatment on physical properties of cocoanut activated carbon

SI Hong-yu1, YANG Li-jun2, SUN Kun-yuan1, LIANG Xiao-hui1, ZHAO Yu-xiao1, ZHANG Xiao-dong1*, ZHANG Yuan-cheng3   

  1. 1.Energy Research Institute, Shandong Academy of Sciences, Jinan 250014, China; 2. Shandong Guanbaolin Carbon Industry Group Co. Ltd., Qingdao 266300, China; 3. Shandong Baoli Biomass Energy Co. Ltd., Dongying 257000, China
  • Received:2016-06-24 Online:2016-12-20 Published:2016-12-20

摘要:

为提高活性炭的吸附性能并降低制备工艺能耗,研究超低温预处理对活性炭品质及其制备工艺的影响,采用液氮对椰壳进行了超低温预处理。通过快速升温活化,在600 ℃下即制得比表面积超过无预处理800 ℃下制得的活性炭,比表面积由1600 m2/g增大至2300 m2/g以上,微孔总体积也由0.67 cm3/g增加至0.92 cm3/g。结果表明,超低温预处理方式对提高活性炭品质和降低工艺能耗都有显著的促进作用,该研究为活性炭功能性开发和表面结构改良研究提供了参考依据。

关键词: 活性炭, 超低温, 快速升温

Abstract:

 To enhance absorption property of activated carbon and reduce energy consumption of preparation technology, we address the impact of ultralow temperature pretreatment on quality and preparation technology of activated carbon. We employ liquid nitrogen to pretreat coconut shell at ultralow temperature. Through rapid temperature rise, we prepare activated carbon at 600 ℃ whose specific surface area surpasses that of nonpretreatment activated carbon at 800 ℃. The specific surface area of activated carbon of the coconut shell increases to 2300 m2/g from 1 600 m2/g, and its micropore volume increases to 0.92 cm3/g from 0.67 cm3/g. Results show that ultralow temperature pretreatment has significant positive effect to quality improvement and reduction of energy consumption of activated carbon. The research provides reference for functional development and  the improvement of surface structure of activated carbon.

Key words: activated carbon, rapid temperature rise, ultra-low temperature

中图分类号: 

  • TQ424.1+5